[3-(Trifluoromethyl)phenyl]phenyliodonium triflate

Base Information

• Chemical Name: [3-(Trifluoromethyl)phenyl]phenyliodonium triflate
• CAS No.: 905718-46-9
• Molecular Formula: CF₃O₃S*C₁₃H₉F₃I
• Molecular Weight: 498.185
• Mol file: 905718-46-9.mol

Synonyms:

Chemical Property of [3-(Trifluoromethyl)phenyl]phenyliodonium triflate

Chemical Property:

• Melting Point: 110.0 to 114.0 °C
• Solubility.: soluble in Methanol

Purity/Quality:

98% ^*data from raw suppliers

Phenyl[3-(trifluoromethyl)phenyl]iodonium Trifluoromethanesulfonate >98.0%(HPLC)(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): 10503310
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

Useful:

Technology Process of [3-(Trifluoromethyl)phenyl]phenyliodonium triflate

There total 6 articles about [3-(Trifluoromethyl)phenyl]phenyliodonium triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

m-trifluoromethylphenyl iodide (401-81-0) + sodium triflate (2926-30-9) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → (3-trifluoromethylphenyl)(phenyl)iodonium triflate (905718-46-9)

Guidance literature:

m-trifluoromethylphenyl iodide; benzene; With dipotassium peroxodisulfate; trifluoroacetic acid; In dichloromethane; at 36 - 38 ℃; for 20h;

sodium triflate; In water; at 20 ℃; for 8h;

DOI:10.1016/j.tet.2006.04.073

Reference yield: 63.0%

trifluorormethanesulfonic acid (1493-13-6) + m-trifluoromethylphenyl iodide (401-81-0) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → (3-trifluoromethylphenyl)(phenyl)iodonium triflate (905718-46-9)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 80 ℃; for 15h;

DOI:10.1002/adsc.200700373

Reference yield: 63.0%

iodobenzene (591-50-4) + trifluorormethanesulfonic acid (1493-13-6) + α,α,α-trifluorotoluene (98-08-8) → (3-trifluoromethylphenyl)(phenyl)iodonium triflate (905718-46-9)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 80 ℃; for 15h;

DOI:10.1002/chem.201201645

upstream raw materials:

m-trifluoromethylphenyl iodide

sodium triflate

benzene

trifluorormethanesulfonic acid

Refernces

• 1、 Legault, Claude Y.,Mayer, Robert J.,Mayr, Herbert,Ofial, Armin R.. "Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases". supporting information. . Retrieved 2020/03/13.
• 2、 Soldatova, Natalia,Postnikov, Pavel,Kukurina, Olga,Zhdankin, Viktor V.,Yoshimura, Akira,Wirth, Thomas,Yusubov, Mekhman S.. "Facile One-Pot Synthesis of Diaryliodonium Salts from Arenes and Aryl Iodides with Oxone". . p. 18 - 20. Retrieved 2017/02/10.