D-2,4-DINITROPHE

Base Information

• Chemical Name: D-2,4-DINITROPHE
• CAS No.: 1217849-53-0
• Molecular Formula: C₉H₉N₃O₆
• Molecular Weight: 255.187
• Mol file: 1217849-53-0.mol

Synonyms:

Chemical Property of D-2,4-DINITROPHE

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

D-2,4-Dinitrophenylalanine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of D-2,4-DINITROPHE

There total 3 articles about D-2,4-DINITROPHE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.8%

4-nitro-3-phenyl-L-alanine (949-99-5) → (2S)-2-amino-3-(2,4-dinitrophenyl)propanoic acid (49607-21-8,1217849-53-0)

Guidance literature:

With sulfuric acid; uronium nitrate; at 0 - 60 ℃; for 5h; Temperature; Reagent/catalyst; Time; regioselective reaction;

DOI:10.1007/s11164-012-0673-z

Reference yield:

L-phenylalanine (63-91-2,25191-15-5,658-69-5,67675-33-6) → (2S)-2-amino-3-(2,4-dinitrophenyl)propanoic acid (49607-21-8,1217849-53-0)

Guidance literature:

With uronium nitrate;

DOI:10.1021/je100352r

Reference yield:

→ 2,4-Dinitro-Phenylalanin (49607-21-8,1217849-53-0)

Guidance literature:

Aus D(-)-Alanin in A., 1-Fluor-2,4-dinitrobenzol, NaHCO3;

DOI:10.1021/jo01344a064

upstream raw materials:

L-phenylalanine

4-nitro-3-phenyl-L-alanine

Refernces

• 1、 Liu, Jin-Qiang,Chen, Xin-Zhi,Ji, Baoming,Zhao, Bang-Tun. "Transformation of l-phenylalanine to (S)-indoline-2-carboxylic acid without group-protection". . p. 1143 - 1152. Retrieved 2013.