N,N’-Bis(2-decyl-tetradecyl)-1,7-dibromo-3,4,9,10-perylene diimide

Base Information

• Chemical Name: N,N’-Bis(2-decyl-tetradecyl)-1,7-dibromo-3,4,9,10-perylene diimide
• CAS No.: 909019-78-9
• Molecular Formula: C₇₂H₁₀₄Br₂N₂O₄
• Molecular Weight: 1221.44
• Mol file: 909019-78-9.mol

Synonyms:

Chemical Property of N,N’-Bis(2-decyl-tetradecyl)-1,7-dibromo-3,4,9,10-perylene diimide

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N’-Bis(2-decyl-tetradecyl)-1,7-dibromo-3,4,9,10-perylene diimide

There total 3 articles about N,N’-Bis(2-decyl-tetradecyl)-1,7-dibromo-3,4,9,10-perylene diimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

2-decyl-1-tetradecylamine (62281-07-6) + 1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride (118129-60-5) → N,N-bis(2-decyl-1-tetradecyl)-1,7-dibromoperylene-3,4,9,10-tetracarboxylic acid bisimide (909019-78-9)

Guidance literature:

In water; butan-1-ol; at 80 ℃; for 17h;

DOI:10.1021/ja071760d

Reference yield: 80.0%

N,N'-bis(2-decyltetradecyl)-3,4,9,10-perylene diimide (1187541-55-4) → N,N-bis(2-decyl-1-tetradecyl)-1,7-dibromoperylene-3,4,9,10-tetracarboxylic acid bisimide (909019-78-9)

Guidance literature:

With bromine; In dichloromethane; at 60 ℃;

DOI:10.1002/pola.27108

Reference yield:

2-decyl-1-tetradecylamine (62281-07-6) + perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride (128-69-8) → N,N-bis(2-decyl-1-tetradecyl)-1,7-dibromoperylene-3,4,9,10-tetracarboxylic acid bisimide (909019-78-9) + ((C10H21)(C12H25)CHCH2N(CO)2C10H3Br)2 + C72H105BrN2O4

Guidance literature:

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride; With iodine; In sulfuric acid; at 85 ℃; for 0.5h;

With bromine; In sulfuric acid; at 85 ℃; for 19h;

2-decyl-1-tetradecylamine; With acetic acid; In 1-methyl-pyrrolidin-2-one; at 85 ℃; for 12h; Inert atmosphere;

DOI:10.1039/c5cc00966a

upstream raw materials:

2-decyl-1-tetradecylamine

1,7-dibromoperylene-3,4,9,10-tetracarboxylic dianhydride

N,N'-bis(2-decyltetradecyl)-3,4,9,10-perylene diimide

perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride

Refernces

• 1、 Tang, Zhonghai,Wei, Xuyang,Zhang, Weifeng,Zhou, Yankai,Wei, Congyuan,Huang, Jianyao,Chen, Zhihui,Wang, Liping,Yu, Gui. "An A?D?A??D? strategy enables perylenediimide-based polymer dyes exhibiting enhanced electron transport characteristics". . . Retrieved 2019.
• 2、 Zhan, Xuejun,Zhang, Ji,Tang, Sheng,Lin, Yuxuan,Zhao, Min,Yang, Jie,Zhang, Hao-Li,Peng, Qian,Yu, Gui,Li, Zhen. "Pyrene fused perylene diimides: Synthesis, characterization and applications in organic field-effect transistors and optical limiting with high performance". supporting information. p. 7156 - 7159. Retrieved 2015/04/27.