WI(N₂Si(CH₃)(OCH₃)2){P(CH₃)2C₆H₅}4

Base Information

• Chemical Name: WI(N₂Si(CH₃)(OCH₃)2){P(CH₃)2C₆H₅}4
• CAS No.: 151037-24-0
• Molecular Formula: C₃₅H₅₃IN₂O₂P₄SiW
• Molecular Weight: 996.553
• Mol file: 151037-24-0.mol

Synonyms:

Chemical Property of WI(N₂Si(CH₃)(OCH₃)2){P(CH₃)2C₆H₅}4

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of WI(N₂Si(CH₃)(OCH₃)2){P(CH₃)2C₆H₅}4

There total 1 articles about WI(N₂Si(CH₃)(OCH₃)2){P(CH₃)2C₆H₅}4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

cis-{tungsten(dinitrogen)2(P(methyl)2Ph)4} + chlorodimethoxymethylsilane (994-07-0) + sodium iodide (7681-82-5,24359-64-6,41927-88-2,115813-40-6) → WI(N2Si(CH3)(OCH3)2){P(CH3)2C6H5}4 (151037-24-0)

Guidance literature:

In benzene; byproducts: NaCl; under N2; the starting complex is added to a degassed mixture (at -40 to -50°C) of the chlorosilane and NaI in benzene, stirred at 50°C for 45 h in the dark; filtd. from NaI and NaCl, the filtrate is concd. in vac., the obtained solid is filtd., washed (hexane), dried in vac., elem. anal.;

DOI:10.1016/0022-328X(93)80428-E

upstream raw materials:

chlorodimethoxymethylsilane

sodium iodide

Refernces