2-Chlorophenanthrene

Base Information

• Chemical Name: 2-Chlorophenanthrene
• CAS No.: 24423-11-8
• Molecular Formula: C₁₄H₉Cl
• Molecular Weight: 212.678
• Hs Code.: 2903998090
• DSSTox Substance ID: DTXSID10179175
• Nikkaji Number: J307.780B
• Wikidata: Q72456340
• ChEMBL ID: CHEMBL1797286
• Mol file: 24423-11-8.mol

Synonyms:2-CHLOROPHENANTHRENE;24423-11-8;phenanthrene, 2-chloro-;2-chloranylphenanthrene;SCHEMBL2723778;CHEMBL1797286;DTXSID10179175;ZAA42311;MFCD13191757;AKOS015851312;BS-16282;CS-0155966;FT-0656379;D82506;A817297;J-509161

Chemical Property of 2-Chlorophenanthrene

Chemical Property:

• Vapor Pressure: 2.42E-05mmHg at 25°C
• Melting Point: 85-85.5 °C(Solv: ethanol (64-17-5))
• Refractive Index: 1.717
• Boiling Point: 370.1 °C at 760 mmHg
• Flash Point: 179.2 °C
• PSA: 0.00000
• Density: 1.253 g/cm³
• LogP: 4.64640
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 5.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 212.0392780
• Heavy Atom Count: 15
• Complexity: 225

Purity/Quality:

98.5% ^*data from raw suppliers

2-Chlorophenanthrene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC3=C2C=CC(=C3)Cl

Technology Process of 2-Chlorophenanthrene

There total 26 articles about 2-Chlorophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4′-chloro-2′-styryl-[1,1′-biphenyl]-2-carbaldehyde → 2-chlorophenanthrene (24423-11-8)

Guidance literature:

With phosphomolybdic acid; In 1,2-dichloro-ethane; at 25 ℃; for 12h; Sealed tube;

DOI:10.1021/acs.joc.1c02385

Reference yield: 85.0%

4'-chloro-2-(2-methoxyethenyl)-1,1'-biphenyl → 2-chlorophenanthrene (24423-11-8)

Guidance literature:

With methanol; iron(III) chloride; In 1,2-dichloro-ethane; at 50 ℃; for 3h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ol5018273

Reference yield: 74.0%

4′-chloro-2-ethynyl-1,1′-biphenyl → 2-chlorophenanthrene (24423-11-8)

Guidance literature:

With silver(I) hexafluorophosphate; [dichloro(p-cymene)(triphenylphosphane)ruthenium(II)]; In chlorobenzene; at -78 - 120 ℃; for 20h; Inert atmosphere;

DOI:10.1002/chem.201500248

upstream raw materials:

2-aminophenanthrene

1-chloro-3-styrylbenzene

2-chlorophenanthren-9-yl trifluoromethanesulfonate

(E)-3-chlorostilbene

Refernces

• 1、 Chen, Yi,Liu, Di,Wang, Rui,Xu, Li,Tan, Jingyao,Shu, Mao,Tian, Lingfeng,Jin, Yuan,Zhang, Xiaoke,Lin, Zhihua. "Br?nsted Acid-Catalyzed Carbonyl-Olefin Metathesis: Synthesis of Phenanthrenes via Phosphomolybdic Acid as a Catalyst". . p. 351 - 362. Retrieved 2022/01/03.
• 2、 -. "NOVEL COMPOUND AND ORGANIC LIGHT EMITTING DEVICE COMPRISING THE SAME". Paragraph 0376. . Retrieved 2018/04/12.