Azidobis(dimethylamino)phosphine oxide

Base Information

• Chemical Name: Azidobis(dimethylamino)phosphine oxide
• CAS No.: 7219-78-5
• Molecular Formula: C₄H₁₂N₅OP
• Molecular Weight: 177.146
• Mol file: 7219-78-5.mol

Synonyms:Phosphorodiamidicazide, tetramethyl- (6CI,7CI,8CI,9CI); Bis(dimethylamino)azidophosphine oxide;Mazidox; N,N,N',N'-Tetramethylphosphorodiamidic azide;Tetramethyldiamidophosphinyl azide; Tetramethylphosphorodiamidic azide

Chemical Property of Azidobis(dimethylamino)phosphine oxide

Chemical Property:

• PSA: 83.11000
• LogP: 0.98076

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Azidobis(dimethylamino)phosphine oxide

There total 1 articles about Azidobis(dimethylamino)phosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N,N',N'-Tetramethylphosphorodiamidic chloride (1605-65-8) → (tetramethyldiamido)azidophosphate (7219-78-5)

Guidance literature:

With sodium azide; water;

Reference yield: 69.0%

(tetramethyldiamido)azidophosphate (7219-78-5) + O,O-diphenyl N-dimethylamidophosphite (19620-78-1) → O,O-diphenyl N-dimethylamido(tetramethyldiamidophosphorylimido)phosphate (75944-10-4)

Guidance literature:

at 100 ℃;

DOI:10.1007/BF00951238

Reference yield:

triphenyl phosphite (101-02-0) + (tetramethyldiamido)azidophosphate (7219-78-5) → triphenyl (tetramethyldiamidophosphorylimido)phosphate

Guidance literature:

110-120 deg C -> 140 deg C, 4 h;

DOI:10.1007/BF00951238

upstream raw materials:

N,N,N',N'-Tetramethylphosphorodiamidic chloride

Downstream raw materials:

O,O-diphenyl N-dimethylamido(tetramethyldiamidophosphorylimido)phosphate