PdCl₃P(C₆H₅)3^(1-)*P(C₆H₅)3(CH₂CH₂COCH₃)⁽¹⁺⁾={PdCl₃P(C₆H₅)3}{P(C₆H₅)3(CH₂CH₂COCH₃)}

Base Information

• Chemical Name: PdCl₃P(C₆H₅)3^(1-)*P(C₆H₅)3(CH₂CH₂COCH₃)⁽¹⁺⁾={PdCl₃P(C₆H₅)3}{P(C₆H₅)3(CH₂CH₂COCH₃)}
• CAS No.: 88325-31-9
• Molecular Formula: C₁₈H₁₅Cl₃PPd*C₂₂H₂₂OP
• Molecular Weight: 808.46
• Mol file: 88325-31-9.mol

Synonyms:

Chemical Property of PdCl₃P(C₆H₅)3^(1-)*P(C₆H₅)3(CH₂CH₂COCH₃)⁽¹⁺⁾={PdCl₃P(C₆H₅)3}{P(C₆H₅)3(CH₂CH₂COCH₃)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PdCl₃P(C₆H₅)3^(1-)*P(C₆H₅)3(CH₂CH₂COCH₃)⁽¹⁺⁾={PdCl₃P(C₆H₅)3}{P(C₆H₅)3(CH₂CH₂COCH₃)}

There total 3 articles about PdCl₃P(C₆H₅)3^(1-)*P(C₆H₅)3(CH₂CH₂COCH₃)⁽¹⁺⁾={PdCl₃P(C₆H₅)3}{P(C₆H₅)3(CH₂CH₂COCH₃)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-chloro-2-butanone (6322-49-2) + bis-triphenylphosphine-palladium(II) chloride (13965-03-2) → PdCl3P(C6H5)3(1-)*P(C6H5)3(CH2CH2COCH3)(1+)={PdCl3P(C6H5)3}{P(C6H5)3(CH2CH2COCH3)} (88325-31-9)

Guidance literature:

With hydrogenchloride; carbon monoxide; In ethanol; React. between Pd-complex, CH3COCH2CH2Cl and EtOH soln. of HCl under 100 atm CO at 80°C for 2 h in an autoclave.; Cooling of autoclave to room temp., slow depressurizing after several hours, filtn. of suspn., washing of ppt. (ethyl ether), drying in vac. Identification of resulting cryst. by elem. and IR anal.;

DOI:10.1016/0304-5102(90)85045-J

Reference yield:

sym,trans-[PdCl2(PPh3)2] + 3-Oxobutyl-triphenylphosphonium-chlorid (43101-00-4) → {PdCl3(P(C6H5)3)}(1-)*{(P(C6H5)3)(CH2CH2COCH3)}(1+) = {PdCl3(P(C6H5)3)}{(P(C6H5)3)(CH2CH2COCH3)} (88325-31-9)

Guidance literature:

In ethanol; Pd-complex was treated with excess of ligand in EtOH; elem. anal.;

DOI:10.1016/S0020-1693(00)91184-8

Reference yield:

4-chloro-2-butanone (6322-49-2) + trans-bis(triphenylphosphine)palladium dichloride (28966-81-6) → {PdCl3(P(C6H5)3)}(1-)*{(P(C6H5)3)(CH2CH2COCH3)}(1+) = {PdCl3(P(C6H5)3)}{(P(C6H5)3)(CH2CH2COCH3)} (88325-31-9)

Guidance literature:

In ethanol; Pd-complex was treated with excess of ligand in boiling EtOH for some h; cooled, allowed to stand, sepd. out;

DOI:10.1016/S0020-1693(00)91184-8

upstream raw materials:

3-Oxobutyl-triphenylphosphonium-chlorid

4-chloro-2-butanone

trans-bis(triphenylphosphine)palladium dichloride

bis-triphenylphosphine-palladium(II) chloride

Refernces