RuHCl(N₂)(PCy₃)2

Base Information

• Chemical Name: RuHCl(N₂)(PCy₃)2
• CAS No.: 220628-21-7
• Molecular Formula: C₃₆H₆₇ClN₂P₂Ru
• Molecular Weight: 726.412
• Mol file: 220628-21-7.mol

Synonyms:

Chemical Property of RuHCl(N₂)(PCy₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuHCl(N₂)(PCy₃)2

There total 2 articles about RuHCl(N₂)(PCy₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1-dichloropropane (78-99-9) + [Ru(H)2(N2)2(PCy3)2] (181782-43-4,155229-91-7) → Ru(H)Cl(N2)(P(C6H11)3)2 (220628-21-7)

Guidance literature:

In benzene-d6; byproducts: 1-chloropropane; inert atmosphere; stirring equimolar amts. for 20 h; not isolated, detd. by (1)H- and (31)P-NMR spectroscopy;

Reference yield:

RuHCl(H2)(PCy3)2 (315675-18-4,133779-04-1) + nitrogen (7727-37-9) → RuHCl(N2)(PCy3)2 (220628-21-7)

Guidance literature:

In not given; identified by NMR;

DOI:10.1021/om800778h

Reference yield:

Ru(H)Cl(N2)(P(C6H11)3)2 (220628-21-7) + hydrogen (1333-74-0) → RuHCl(H2)(tricyclohexylphosphane)2

Guidance literature:

In benzene-d6; inert atmosphere; filling NMR tube with Ru-complex (frozen in liquid N2)with 1 atm H2; not isolated, detd. by (1)H- and (31)P-NMR spectroscopy (after 20 min);

upstream raw materials:

1,1-dichloropropane

[Ru(H)₂(N₂)₂(PCy₃)₂]

RuHCl(H₂)(PCy₃)2

nitrogen

Refernces

• 1、 Olivan, Montserrat,Caulton, Kenneth G.. "C-(halide) oxidative addition routes to ruthenium carbenes". . p. 566 - 570. Retrieved 2008/10/08.