triethylammonium bis(triphenylphosphine)iminium tris(2-mercapto-4-methylphenolato)vanadate(IV)

Base Information

• Chemical Name: triethylammonium bis(triphenylphosphine)iminium tris(2-mercapto-4-methylphenolato)vanadate(IV)
• CAS No.: 172483-48-6
• Molecular Formula: C₆H₁₆N*C₂₁H₁₈O₃S₃V*C₃₆H₃₀NP₂
• Molecular Weight: 1106.3
• Mol file: 172483-48-6.mol

Synonyms:

Chemical Property of triethylammonium bis(triphenylphosphine)iminium tris(2-mercapto-4-methylphenolato)vanadate(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of triethylammonium bis(triphenylphosphine)iminium tris(2-mercapto-4-methylphenolato)vanadate(IV)

There total 1 articles about triethylammonium bis(triphenylphosphine)iminium tris(2-mercapto-4-methylphenolato)vanadate(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

bis(acetylacetonate)oxovanadium (3153-26-2) + 4-methyl-2-mercaptophenol (60774-07-4) + bis(triphenylphosphine)iminium chloride (21050-13-5) + triethylamine (121-44-8) → triethylammonium tris(2-mercapto-4-methylphenolato)vanadate(IV) + triethylammonium bis(triphenylphosphine)iminium tris(2-mercapto-4-methylphenolato)vanadate(IV) (172483-48-6)

Guidance literature:

In acetonitrile; inert atmosphere; treatment of V-complex with 3 equiv. ligand for 30 min, evapn. Et3N addn., stirring overnight, solvent removal, dissoln. in MeOH, filtration, addn. of PPNCl; pptn. on Et2O addn., recrystn. (MeOH/Et2O); elem. anal.;

upstream raw materials:

bis(acetylacetonate)oxovanadium

4-methyl-2-mercaptophenol

bis(triphenylphosphine)iminium chloride

triethylamine

Refernces