3-Methyl-2-butenylphenyl ether

Base Information

• Chemical Name: 3-Methyl-2-butenylphenyl ether
• CAS No.: 14309-15-0
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Hs Code.: 2909309090
• Mol file: 14309-15-0.mol

Synonyms:Ether,3-methyl-2-butenyl phenyl;3-Methyl-2-butenylphenyl ether;

Chemical Property of 3-Methyl-2-butenylphenyl ether

Chemical Property:

• PSA: 9.23000
• LogP: 3.03160

Purity/Quality:

99.9% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Methyl-2-butenylphenyl ether

There total 32 articles about 3-Methyl-2-butenylphenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

prenyl bromide (870-63-3) + phenol (108-95-2,27073-41-2) → phenyl prenyl ether (14309-15-0)

Guidance literature:

at 170 ℃;

DOI:10.1002/ejoc.201000738

Reference yield: 100.0%

O-prenyl-2-iodophenol (120568-94-7) → phenyl prenyl ether (14309-15-0)

Guidance literature:

With lithium trimethylmanganate;

DOI:10.1246/bcsj.70.2039

Reference yield: 86.0%

Diisobutyl-(3-methyl-but-2-enyl)-telluronium; bromide + phenol (108-95-2,27073-41-2) → phenyl prenyl ether (14309-15-0)

Guidance literature:

With sodium hydroxide; In tetrahydrofuran; for 5h; Ambient temperature;

DOI:10.1080/00397919308012585

upstream raw materials:

prenyl bromide

phenol

sodium phenoxide

3-nitrophthalic acid anhydride

Downstream raw materials:

2,2-dichloro-3,3-dimethyl-4-(phenoxymethyl)cyclobutanone

isopentyl phenyl ether

2-chloro-4-phenoxy-2-methyl-3-nitrosobutane

2,2-dimethyl-3-(phenoxymethyl)oxirane

Refernces

• 1、 Mitsudo, Koichi,Nakagawa, Yumiko,Mizukawa, Jun-Ichi,Tanaka, Hideo,Akaba, Ryoichi,Okada, Takahiro,Suga, Seiji. "Electro-reductive cyclization of aryl halides promoted by fluorene derivatives". . p. 444 - 449. Retrieved 2012.
• 2、 Fujitani, Tadahiro,Hong, Dachao,Ito, Satoru,Ji, Xinyi,Kon, Yoshihiro,Nakashima, Takuya,Osuga, Ryota,Sato, Kazuhiko,Yokoi, Toshiyuki. "Chemoselective Epoxidation of Allyloxybenzene by Hydrogen Peroxide Over MFI-Type Titanosilicate". supporting information. . Retrieved 2020/04/15.
• 3、 Pan, Le,Lei, Dongyu,Jin, Lu,He, Yuan,Yang, Qingqing. "Promising fungicides from allelochemicals: Synthesis of umbelliferone derivatives and their structure–activity relationships". . . Retrieved 2018/11/24.