N,N'-bis(3-diphenylstibinopropyl)-N,N'-dimethylethylenediamine

Base Information

• Chemical Name: N,N'-bis(3-diphenylstibinopropyl)-N,N'-dimethylethylenediamine
• CAS No.: 80215-32-3
• Molecular Formula: C₃₄H₄₂N₂Sb₂
• Molecular Weight: 722.221
• Mol file: 80215-32-3.mol

Synonyms:

Chemical Property of N,N'-bis(3-diphenylstibinopropyl)-N,N'-dimethylethylenediamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-bis(3-diphenylstibinopropyl)-N,N'-dimethylethylenediamine

There total 1 articles about N,N'-bis(3-diphenylstibinopropyl)-N,N'-dimethylethylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

LiSb(C6H5)2 (55085-09-1) + N,N'-dimethyl-N,N'-bis(3-chloropropyl)ethylenediamine (80191-97-5) → N,N'-bis(3-diphenylstibinopropyl)-N,N'-dimethylethylenediamine (80215-32-3)

Guidance literature:

In tetrahydrofuran; under N2, the mixt. was hydrolysed when the red colour was discharged; the organic layer sepd., dried and evapd. to yield an oil, which added to NiBr2*H2O/butanol and heated for 1 h, then evapd., extd. with Et2O, petroleum ether, the washings were discarded, rest refluxed with NH3 for 4 h, cooled, extd., evapd., dried;

DOI:10.1016/S0022-328X(00)83008-9

Reference yield:

sodium tetrachloropalladate(II) + N,N'-bis(3-diphenylstibinopropyl)-N,N'-dimethylethylenediamine (80215-32-3) → ((C6H5)2SbCH2CH2CH2N(CH3)CH2)2*2Pd(2+)*4Cl(1-)=((C6H5)2SbCH2CH2CH2N(CH3)CH2)2Pd2Cl4

Guidance literature:

In ethanol; 1 h under N2; the soln. was concd. in vac., the solid filtered off and dried; elem. anal.;

DOI:10.1016/S0022-328X(00)83008-9

upstream raw materials:

LiSb(C₆H₅)2

N,N'-dimethyl-N,N'-bis(3-chloropropyl)ethylenediamine

Refernces