METHYL 6-TRANS-OCTADECENOATE

Base Information

• Chemical Name: METHYL 6-TRANS-OCTADECENOATE
• CAS No.: 14620-36-1
• Molecular Formula: C19H36O2
• Molecular Weight: 296.494
• Mol file: 14620-36-1.mol

Synonyms:Petroselaidic acid ethyl ester;Methyl Petroselaidate;Octadec-6t-ensaeure-aethylester;octadec-6t-enoic acid ethyl ester;Petrolselaidinsaeureethylester;trans-6-Octadecenoic Acid Methyl Ester;Octadec-6t-ensaeure-methylester;Methyl trans-6-Octadecenoate;Ethyl petroselaidate;octadec-6t-enoic acid methyl ester;Petroselaidinsaeureethylester;

Chemical Property of METHYL 6-TRANS-OCTADECENOATE

Chemical Property:

• Vapor Pressure: 1.07E-05mmHg at 25°C
• Melting Point: 19°C(lit.)
• Refractive Index: 1.4490 to 1.4530
• Boiling Point: 370.9oC at 760 mmHg
• Flash Point: 92.4oC
• PSA: 26.30000
• Density: 0.873g/cm3
• LogP: 6.19690
• Storage Temp.: ?20°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methyl trans-6-Octadecenoate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn,N
• Statements: 11-38-50/53-65-67
• Safety Statements: 9-16-29-33-60-61-62

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL 6-TRANS-OCTADECENOATE

There total 4 articles about METHYL 6-TRANS-OCTADECENOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl linoleate (18287-20-2) → methyl petroselinate (2777-58-4) + methyl 6(E)-octadecenoate (14620-36-1) + Methyl oleate (112-62-9) + methyl (9E)-octadec-9-enoate (2462-84-2) + Methyl stearate (112-61-8) + trans-methyl 8-octadecenoate (26528-50-7)

Guidance literature:

With hydrogen; palladium; In ethanol; at 24 ℃; Product distribution; potencial controlled catalytic hydrogenation of other unsaturated fatty acid esters, effects of potential, electrolytes, solvents, double bond distribution;

Reference yield:

methyl petroselinate (2777-58-4) → methyl 6(E)-octadecenoate (14620-36-1)

Guidance literature:

With methanesulfonyl chloride; In ethanol; water; at 22 ℃; G-values; γ-Irradiation;

DOI:10.1021/ja070626q

Reference yield:

methanol (67-56-1) + Petroselaidic acid (593-40-8) → methyl 6(E)-octadecenoate (14620-36-1)

Guidance literature:

With sulfuric acid;

upstream raw materials:

methanol

Petroselaidic acid

methyl linoleate

methyl petroselinate

Refernces

• 1、 Froeling, A.,Hornung, F.,Jongh, R. O. de. "Potentional-controlled catalytic hydrogenation. Effect of palladium catalyst potential on the selectivity of hydrogenation of polyunsaturated fatty acid esters". . p. 123 - 128. Retrieved 2007/10/02.