(fac)-Fe(methylchloroglyoximato)3(BC₆H₅)2

Base Information

• Chemical Name: (fac)-Fe(methylchloroglyoximato)3(BC₆H₅)2
• CAS No.: 835618-95-6
• Molecular Formula: C₂₁H₁₉B₂Cl₃FeN₆O₆
• Molecular Weight: 635.246
• Mol file: 835618-95-6.mol

Synonyms:

Chemical Property of (fac)-Fe(methylchloroglyoximato)3(BC₆H₅)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (fac)-Fe(methylchloroglyoximato)3(BC₆H₅)2

There total 1 articles about (fac)-Fe(methylchloroglyoximato)3(BC₆H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Fe(CH3CN)4Cl2] (227027-67-0) + N-hydroxy-2-(hydroxyimino)propanimidoyl chloride (4732-59-6) + phenylboronic acid (98-80-6) → (fac)-Fe(methylchloroglyoximato)3(BC6H5)2 (835618-95-6) + (mer)-Fe(methylchloroglyoximato)3(BC6H5)2 (835618-94-5)

Guidance literature:

In nitromethane; phenylboronic acid and 10% excess of glyoxime were dissolved/suspnd. in dry CH3NO2, the mixt. was refluxed for 30 min with partial evapn., Fe(CH3CN)4Cl2 was added, the mixt. was stirred and refluxed for 5 h; ppt. was isolated, washed with hot water, methanol, diethyl ether and then hexane,. dried in vac.; elem. anal.;

DOI:10.1016/j.ica.2004.08.008

Reference yield:

(fac)-Fe(methylchloroglyoximato)3(BC6H5)2 (835618-95-6) + (mer)-Fe(methylchloroglyoximato)3(BC6H5)2 (835618-94-5) + n-butanethiol (109-79-5) → (fac)-Fe((n-butanethio)methylglyoximato)3(BC6H5)2 (835619-02-8) + (mer)-Fe((n-butanethio)methylglyoximato)3(BC6H5)2 (835619-01-7)

Guidance literature:

With triethyl amine; In N,N-dimethyl-formamide; benzene; an excess of C4H9SH and triethylamine in DMF was added dropwise to a stirred soln./suspn. of complex in DMF-benzene, the mixt. was stirred at 60°C for 20 h; evapd.,pptn. with 5-fold volume of H2O, filtered off, washed with CH3OH-H2O, CH3OH dried in vac., dissolved in CH2Cl2, filtered through SilasorbSPH-300, evapd. to dryness, washed with hexane, dried in vac., elem. an al.;

DOI:10.1016/j.ica.2004.08.008

Reference yield:

(fac)-Fe(methylchloroglyoximato)3(BC6H5)2 (835618-95-6) + (mer)-Fe(methylchloroglyoximato)3(BC6H5)2 (835618-94-5) + N-butylamine (109-73-9,85404-21-3) → (mer,mer)-Fe(methylchloroglyoximato)(methyl(n-butylamino)glyoximato)2(BC6H5)2 + (fac,fac)-Fe(methylchloroglyoximato)(methyl(n-butylamino)glyoximato)2(BC6H5)2 (835618-99-0) + (mer,fac)-Fe(methylchloroglyoximato)(methyl(n-butylamino)glyoximato)2(BC6H5)2 (835619-00-6)

Guidance literature:

In N,N-dimethyl-formamide; an excess of C4H9NH2 was added to a soln./suspn. of complex in DMF, the mixt. was stirred at 60°C for 30 min, filtered, heated at 60°C for 6 h; pptn. with 4-fold volume of water, solid was filtered off, washed with ethanol-water, dried in vac., dissolved in CH2Cl2, filtered through Silasorb SPH-300, evapd. to a small vol., pptn. with hexane, washed with hexane, dried in vac., elem. anal.;

DOI:10.1016/j.ica.2004.08.008

upstream raw materials:

[Fe(CH₃CN)₄Cl₂]

N-hydroxy-2-(hydroxyimino)propanimidoyl chloride

phenylboronic acid

Downstream raw materials:

(fac,fac)-Fe(methylchloroglyoximato)(methyl(n-butylamino)glyoximato)2(BC₆H₅)2

(mer,fac)-Fe(methylchloroglyoximato)(methyl(n-butylamino)glyoximato)2(BC₆H₅)2

(fac)-Fe((n-butanethio)methylglyoximato)3(BC₆H₅)2

(mer)-Fe((n-butanethio)methylglyoximato)3(BC₆H₅)2

Refernces