Rhodium, carbonylchlorobis(triphenylarsine)-

Base Information

• Chemical Name: Rhodium, carbonylchlorobis(triphenylarsine)-
• CAS No.: 14877-90-8
• Molecular Formula: C₃₇H₃₀As₂ClORh
• Molecular Weight: 778.846
• Mol file: 14877-90-8.mol

Synonyms:

Chemical Property of Rhodium, carbonylchlorobis(triphenylarsine)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rhodium, carbonylchlorobis(triphenylarsine)-

There total 2 articles about Rhodium, carbonylchlorobis(triphenylarsine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

di(rhodium)tetracarbonyl dichloride + triphenyl-arsane (603-32-7) → trans-chlorocarbonylbis(triphenylarsine)rhodium(I) (14877-90-8,16970-35-7)

Guidance literature:

In acetone; react. of Rh-contg. compd. with 4.4 equiv. of ligand in acetone soln.;

DOI:10.1016/S0020-1693(03)00436-5

Reference yield: 68.0%

RhCl(AsPh3)3 (14973-92-3) → RhCl(CO)(AsPh3)2 (14877-90-8,16970-35-7)

Guidance literature:

With carbon oxide sulfide; In benzene; byproducts: SAs(C6H5)3; bubbling of COS into soln. (benzene) of Rh-complex (2 h), stirring (2 h), keeping overnight, under N2; addn. of methanol, centrifugation, washing (successively with methanol, ether), drying in vacuo;

Reference yield: 87.0%

RhCl(CO)(AsPh3)2 (14877-90-8,16970-35-7) + silver perchlorate → Rh(CO)(As(C6H5)3)2(CH3COCH3)(1+)*ClO4(1-)=[Rh(CO)(As(C6H5)3)2(CH3COCH3)][ClO4] (75215-13-3)

Guidance literature:

With acetone; In acetone; byproducts: AgCl; silver compd. added to metal compd. soln. in acetone, stirred for 5 min; ppt. sepd. solvent removed to a small volume, diethyl ether added, product crystd.; elem.anal.;

DOI:10.1039/DT9800001259

upstream raw materials:

RhCl(AsPh₃)3

triphenyl-arsane

Downstream raw materials:

trans-Rh(AsPh₃)2(CO)(triflate)

{(C₆H₅)3As}2Rh(CO)ClBBr₃

C₆H₅CH₂CH₂C₂Pt(P(C₆H₅)2CH₂P(C₆H₅)2)2C₂C₆H₅CH₂CH₂RhCO⁽¹⁺⁾*Cl^(1-)=(C₂C₆H₅CH₂CH₂)Pt(P(C₆H₅)2CH₂P(C₆H₅)2)2C₂C₆H₅CH₂CH₂RhCOCl

carbonyl(bis(2-(diphenylarsino)ethyl)benzylamine)rhodium(I)chloride

Refernces

• 1、 Otto, Stefanus,Roodt, Andreas. "Quantifying the electronic cis effect of phosphine, arsine and stibine ligands by use of rhodium(I) Vaska-type complexes". . p. 1 - 10. Retrieved 2008/10/09.