2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl methacrylate

Base Information

• Chemical Name: 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl methacrylate
• CAS No.: 2261-99-6
• Molecular Formula: C11H8 F12 O2
• Molecular Weight: 400.164
• Hs Code.: 29161400
• European Community (EC) Number: 218-863-9
• DSSTox Substance ID: DTXSID70177132
• Nikkaji Number: J213.151J
• Wikidata: Q72470295
• Mol file: 2261-99-6.mol

Synonyms:2261-99-6;1H,1H,7H-Dodecafluoroheptyl methacrylate;2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl methacrylate;1H,1H,7H-Perfluoroheptyl methacrylate;2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl 2-methylprop-2-enoate;1H,1H,7H-DODECAFLUOROHEPTYLMETHACRYLATE;(6H-Perfluorohexyl)methyl methacrylate;C11H8F12O2;EINECS 218-863-9;2-Propenoic acid, 2-methyl-, 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptylester;SCHEMBL285648;DTXSID70177132;BBL103743;MFCD00080658;STL557553;AKOS016015557;C11-H8-F12-O2;GS-6051;D4990;FT-0607843;H10511;A816286;2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptane-1-ol methacrylate;Methacrylic Acid 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl Ester;2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl Methacrylate (stabilized with TBC);2-methyl-acrylic acid 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-heptyl ester

Chemical Property of 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl methacrylate

Chemical Property:

• Refractive Index: 1.349
• Boiling Point: 223.5 °C at 760 mmHg
• Flash Point: 86.6 °C
• PSA: 26.30000
• Density: 1.457 g/cm³
• LogP: 4.54730
• Storage Temp.: Keep Cold
• XLogP3: 5.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 9
• Exact Mass: 400.0332674
• Heavy Atom Count: 25
• Complexity: 525

Purity/Quality:

98%,99%, ^*data from raw suppliers

1H,1H,7H-DodecafluoroheptylMethacrylate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 36/37/38-23/24/25
• Safety Statements: 26-36/37/39-28

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C(=O)OCC(C(C(C(C(C(F)F)(F)F)(F)F)(F)F)(F)F)(F)F

Technology Process of 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl methacrylate

There total 5 articles about 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.5%

potassium methacrylate (6900-35-2) + 2,2,3,3,4,4,5,5,6,6,7,7-Dodecafluoroheptyl chlorosulfite (254756-56-4) → 1H,1H,7H-dodecafluoroheptyl methacrylate (2261-99-6)

Guidance literature:

DOI:10.1023/A:1020788902312

Reference yield: 50.8%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol (335-99-9) → 1H,1H,7H-dodecafluoroheptyl methacrylate (2261-99-6)

Guidance literature:

With hydroquinone; sulfonated coal; sulfuric acid;

Reference yield:

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol (335-99-9) + Methacryloyl chloride (920-46-7,26937-45-1) → 1H,1H,7H-dodecafluoroheptyl methacrylate (2261-99-6)

Guidance literature:

With sulfuric acid; hydroquinone;

upstream raw materials:

2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoro-1-heptanol

Methacryloyl chloride

poly(methacrylic acid)

potassium methacrylate

Refernces

• 1、 -. "EXTERNAL PREPARATION FOR THE SKIN AND COPOLYMER TO BE USED THEREIN". Page/Page column 9. . Retrieved 2008/06/13.
• 2、 Gol'din, G. S.,Averbakh, K. O.,Nekrasova, L. A.. "ORGANOFLUORINE DERIVATIVES OF SALTS OF SULFOCARBOXYLATE ESTERS". . p. 1463 - 1467. Retrieved 2007/10/02.