Ethenyl, 1-methyl-

Base Information

• Chemical Name: Ethenyl, 1-methyl-
• CAS No.: 15552-77-9
• Molecular Formula: C3H5
• Molecular Weight: 41.0727
• Mol file: 15552-77-9.mol

Synonyms:

Chemical Property of Ethenyl, 1-methyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethenyl, 1-methyl-

There total 12 articles about Ethenyl, 1-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

iron monocarbonyl cation (35038-14-3) + 3-chloroprop-1-ene (107-05-1) → FeCl(1+) + C6H10(1+) + FeC3H5Cl(1+) (119909-88-5) + prop-1->3-enylium (1724-46-5,1981-80-2,6067-68-1,15552-77-9,50457-57-3,50457-58-4,65887-19-6,65887-20-9) + iron (1+) (14067-02-8)

Guidance literature:

In gas; reaction with allyl chloride (ca. 1 mTorr) in MS/MS/MS multiquadropole spectrometer (collision gas Ar, 0.7 mTorr; 15-25 eV); according to Beaugrand, C. et al., Int. J. Mass Spectrom. Ion Proc., in press; further products; Kinetics;

DOI:10.1021/ja00191a080

Reference yield:

2-methyl-3,4-diazapenta-1,3-diene (4101-44-4) → methyl radical (2229-07-4) + N-methylmethanimine (1761-67-7) + 2-propenyl radical (15552-77-9) + acetonitrile (75-05-8,26809-02-9)

Guidance literature:

In gaseous matrix; at 501.9 - 656.9 ℃; under 0.001 - 0.01 Torr;

DOI:10.1016/S0040-4039(00)85337-X

Reference yield:

2-methyl-3,4-diazapenta-1,3-diene (4101-44-4) → methyl radical (2229-07-4) + 1,2-propanediene (463-49-0) + 2-propenyl radical (15552-77-9) + prop-1-yne (74-99-7)

Guidance literature:

In gaseous matrix; at 656.9 - 901.9 ℃; under 0.001 - 0.01 Torr; Further byproducts given;

DOI:10.1016/S0040-4039(00)85337-X

upstream raw materials:

(Z)-2-Butene

trans-2-propenyl bromide

isobutene

propene

Downstream raw materials:

formaldehyd

methyl radical

carbon monoxide

prop-1-yne

Refernces

• 1、 Forte, Leonard,Lien, Min H.,Hopkinson, Alan C.,Bohme, Diethard K.. "Gas-phase measurements of the kinetics of BF2(+)-induced polymerization of olefinic monomers". . p. 1576 - 1583. Retrieved 2007/10/02.
• 2、 Ziegler, U.,Zimmermann, G.,Ondruschka, B.,Volkova, V. V.,Gusel'nikov, L. E.,et al.. "MATRIX ISOLATION AND IR SPECTROSCOPIC STUDY OF THE PYROLYSIS PRODUCTS OF 2-METHYL-3,4-DIAZAPENTA-1,3-DIENE. CLEAVAGE OF N=N-BOND IN UNSATURATED AZO COMPOUNDS". . p. 5825 - 5828. Retrieved 2007/10/02.