Allylmagnesium chloride

Base Information

• Chemical Name: Allylmagnesium chloride
• CAS No.: 2622-05-1
• Molecular Formula: C3H5ClMg
• Molecular Weight: 100.831
• Hs Code.: 29319090
• Mol file: 2622-05-1.mol

Synonyms:Allylmagnesiumchloride (6CI);Magnesium, allylchloro- (7CI,8CI);Magnesium,chloro-2-propenyl- (9CI);Allylchloromagnesium;

Chemical Property of Allylmagnesium chloride

Chemical Property:

• Appearance/Colour: clear tan to brown, amber, dark grey, dark green
• Melting Point: -21°C
• Boiling Point: 66°C
• Flash Point: 1 °F
• PSA: 0.00000
• Density: 0.995 g/mL at 25 °C
• LogP: 1.82950
• Storage Temp.: water-free area
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: vigorous reaction

Purity/Quality:

99% ^*data from raw suppliers

AllylmagnesiumChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C
• Statements: 11-14/15-34-40-37-19
• Safety Statements: 16-26-36/37/39-43-45-7/8-6A-43B-33

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.Grignard-reactions: reagent for the introduction of the allyl group. Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

Technology Process of Allylmagnesium chloride

There total 10 articles about Allylmagnesium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

3-chloroprop-1-ene (107-05-1) → allylmagnesium bromide (2622-05-1)

Guidance literature:

With magnesium; In tetrahydrofuran; at 15 ℃; for 0.166667h; Inert atmosphere; Flow reactor;

DOI:10.1021/acs.oprd.9b00493

Reference yield: 91.0%

→ allylmagnesium bromide (2622-05-1)

Guidance literature:

Reference yield: 67.0%

magnesium anthracene + 3-chloroprop-1-ene (107-05-1) → allylmagnesium bromide (2622-05-1)

Guidance literature:

In tetrahydrofuran; methanol;

upstream raw materials:

9,10-dihydro-9,10-anthracendiyl-tris(THF)magnesium

3-chloroprop-1-ene

ethylmagnesium bromide

Dichloromethylsilane

Downstream raw materials:

1-(3,4-dimethoxy-phenyl)-but-3-en-1-ol

2-methyl-1,5-hexadiene

methyldiallylsilane

Trimethyl-[(E)-1-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dienyloxy]-silane

Refernces

• 1、 Jennings, J. R.. "A NOVEL, CONTINUOUS HIGH-YIELD SYNTHESIS OF GRIGNARD REAGENTS". . p. 25 - 30. Retrieved 1987.
• 2、 Fedushkin, Igor L.,Dodonov, Vladimir A.,Skatova, Alexandra A.,Sokolov, Vladimir G.,Piskunov, Alexander V.,Fukin, Georgii K.. "Redox-Active Ligand-Assisted Two-Electron Oxidative Addition to Gallium(II)". . p. 1877 - 1889. Retrieved 2018/01/27.