Vanadium, bis[2-[[(4-methoxyphenyl)imino]methyl]phenolato]oxo-

Base Information

• Chemical Name: Vanadium, bis[2-[[(4-methoxyphenyl)imino]methyl]phenolato]oxo-
• CAS No.: 16743-78-5
• Molecular Formula: C₂₈H₂₄N₂O₅V
• Molecular Weight: 519.45
• Mol file: 16743-78-5.mol

Synonyms:

Chemical Property of Vanadium, bis[2-[[(4-methoxyphenyl)imino]methyl]phenolato]oxo-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Vanadium, bis[2-[[(4-methoxyphenyl)imino]methyl]phenolato]oxo-

There total 2 articles about Vanadium, bis[2-[[(4-methoxyphenyl)imino]methyl]phenolato]oxo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

oxovanadium(IV) sulfate + m-methoxyphenylsalicylaldimine (889-29-2) → VO(CH3OC6H4NCHC6H4O)2 (16743-78-5)

Guidance literature:

In ethanol; water; mixing ethanolic soln. of Schiff base and aq. vanadyl sulfate soln.; addn. of excess of water; immediate pptn.; filtration; washing (water, 50% ethanol); drying over P2O5 in vac. desiccator; elem. anal.;

Reference yield:

vanadyl(IV) sulphate pentahydrate + salicylidene-4-anisidine (889-08-7,116546-10-2,117909-25-8) → [VO(OC6H4CHNC6H4OCH3)2] (16743-78-5)

Guidance literature:

With sodium acetate; In ethanol; water; mixing stoich. amts. of aq. VOSO4 and Schiff base (in EtOH), addn. of AcONa, boiling; collection (filtration); elem. anal.;

DOI:10.1039/DT9770000139

upstream raw materials:

m-methoxyphenylsalicylaldimine

salicylidene-4-anisidine