9-(4-NITROPHENYL)-9H-CARBAZOLE

Base Information

• Chemical Name: 9-(4-NITROPHENYL)-9H-CARBAZOLE
• CAS No.: 16982-76-6
• Molecular Formula: C18H12N2O2
• Molecular Weight: 288.305
• Hs Code.: 2933990090
• Mol file: 16982-76-6.mol

Synonyms:9-(4-nitro-phenyl)-9H-carbazole;N-(4-nitrophenyl)carbazole;nitrophenylnorharman;N-(p-nitrophenyl)carbazole;9-(4'-nitrophenyl)-9H-pyrido[3,4-b]indole;9H-carbazole,9-(4-nitrophenyl);

Chemical Property of 9-(4-NITROPHENYL)-9H-CARBAZOLE

Chemical Property:

• Vapor Pressure: 2.87E-07mmHg at 25°C
• Boiling Point: 420.2oC at 760 mmHg
• Flash Point: 207.9oC
• PSA: 50.75000
• Density: 1.28g/cm3
• LogP: 5.21510

Purity/Quality:

NLT 98% ^*data from raw suppliers

9-(4-Nitrophenyl)carbazole 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9-(4-NITROPHENYL)-9H-CARBAZOLE

There total 14 articles about 9-(4-NITROPHENYL)-9H-CARBAZOLE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + 4-Fluoronitrobenzene (350-46-9,178603-76-4) → 9-(4-nitrophenyl)-9H-carbazole (16982-76-6)

Guidance literature:

With cesium fluoride; In dimethyl sulfoxide; at 150 ℃; for 15h;

DOI:10.1039/b602133f

Reference yield: 98.0%

p-nitrobenzene iodide (636-98-6) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9-(4-nitrophenyl)-9H-carbazole (16982-76-6)

Guidance literature:

With potassium phosphate; (S,S)-1,2-diaminocyclohexane; copper(l) iodide; In 1,4-dioxane; for 24h; Heating;

DOI:10.1080/15421400601013445

Reference yield: 88.0%

9H-carbazole (86-74-8,105184-46-1,97960-57-1) + para-nitrophenyl bromide (586-78-7) → 9-(4-nitrophenyl)-9H-carbazole (16982-76-6)

Guidance literature:

With copper(l) iodide; potassium carbonate; In N,N-dimethyl-formamide; at 155 ℃; for 24h;

DOI:10.1002/pola.24423

upstream raw materials:

9H-carbazole

4-chlorobenzonitrile

carbazole nitranion

4-Fluoronitrobenzene

Downstream raw materials:

4,4'-diamino-4-(3,6-di-tert-butylcarbazol-9-yl)triphenylamine

C₃₈H₃₆N₄O₄

4-(9H-carbazol-9-yl)-N,N-diphenylaniline

9-([1,1’-biphenyl]-4-yl)-9H-carbazole

Refernces

• 1、 Chen, Yen-Chun,Huang, Guo-Sheng,Hsiao, Chung-Chin,Chen, Show-An. "High triplet energy polymer as host for electrophosphorescence with high efficiency". . p. 8549 - 8558. Retrieved 2006.
• 2、 Hsiao, Sheng-Huei,Chiu, Yu-Ting. "Electrosynthesis and electrochromic properties of poly(amide-triarylamine)s containing triptycene units". . p. 90941 - 90951. Retrieved 2015.
• 3、 Liou, Guey-Sheng,Hsiao, Sheng-Huei,Chen, Hwei-Wen. "Novel high-Tg poly(amine-imide)s bearing pendent N-phenylcarbazole units: Synthesis and photophysical, electrochemical and electrochromic properties". . p. 1831 - 1842. Retrieved 2006.
• 4、 Li, Fen,Li, Xiaohui,Wang, Ying,Zhang, Xin. "Fluorescent carbazole-containing dyes: Synthesis and supramolecular assembly by self-complementary donor-acceptor π-stacking and dipolar interactions". . . Retrieved 2020.
• 5、 Zhang, Bin,Liu, Yi-Liang,Chen, Yu,Neoh, Koon-Gee,Li, Yong-Xi,Zhu, Chun-Xiang,Tok, Eng-Soon,Kang, En-Tang. "Nonvolatile rewritable memory effects in graphene oxide functionalized by conjugated polymer containing fluorene and carbazole units". . p. 10304 - 10311. Retrieved 2011.
• 6、 Wang, Hui,Ryu, Jeong-Tak,Han, Yoon Soo,Kim, Dae-Hwan,Choi, Byeong Dae,Kwon, Younghwan. "Synthesis and optical properties of copolymers containing carbazole and 1,3,4-oxadiazole groups as blue host matrix and charge transport materials for polymer light emitting devices". . p. 3 - 13. Retrieved 2007.
• 7、 Niu, Lijuan,Li, Peipei,Chen, Yu,Wang, Jun,Zhang, Jinjuan,Zhang, Bin,Blau, Werner J.. "Conjugated polymer covalently modified multiwalled carbon nanotubes for optical limiting". . p. 101 - 109. Retrieved 2011.
• 8、 Liu, Yu,Chao, Danming,Yao, Hongyan. "New triphenylamine-based poly(amine-imide)s with carbazole-substituents for electrochromic applications". . p. 1422 - 1431. Retrieved 2014.
• 9、 Kundu, Anu,Kumar, Vadivel Vinod,Anthony, Savarimuthu Philip. "Metal-organic frameworks derived CuONPs@C nanocatalysts for synthesizing optoelectronic triarylamine molecules". . . Retrieved 2020/11/05.
• 10、 -. "ORGANIC COMPOUND, AND RADICAL POLYMERIZATION INITIATOR AND CURABLE COMPOSITION CONTAINING THE SAME". Paragraph 0103-0106. . Retrieved 2021/08/31.