3-Vinylcyclohexanone

Base Information

• Chemical Name: 3-Vinylcyclohexanone
• CAS No.: 1740-63-2
• Molecular Formula: C8H12O
• Molecular Weight: 124.183
• Hs Code.: 2914299000
• Mol file: 1740-63-2.mol

Synonyms:Cyclohexanone,3-ethenyl;Cyclohexanone,3-vinyl;3-vinyl-cyclohexan-1-one;3-Vinylcyclohexanone;

Chemical Property of 3-Vinylcyclohexanone

Chemical Property:

• PSA: 17.07000
• LogP: 1.93170

Purity/Quality:

95% ^*data from raw suppliers

3-Vinylcyclohexanone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-Vinylcyclohexanone

There total 24 articles about 3-Vinylcyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

cyclohexenone (930-68-7) + potassium vinyltrifluoroborate → 3-vinylcyclohexanone (1740-63-2)

Guidance literature:

With bis(1,5-cyclooctadiene)rhodium(I) hexafluorophosphate; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; In water; toluene; at 105 - 110 ℃; for 2h;

DOI:10.1002/1099-0690(200211)2002:21<3552::AID-EJOC3552>3.0.CO;2-4

Reference yield: 95.0%

cyclohexenone (930-68-7) + C9H10CuO2S(1-)*Br(1-)*Mg(2+) → methylphenylsulfonate (3112-85-4) + 3-vinylcyclohexanone (1740-63-2)

Guidance literature:

With ammonium chloride; In tetrahydrofuran; at 0 ℃;

DOI:10.1039/c39820000358

Reference yield: 95.0%

cyclohexenone (930-68-7) → 3-vinylcyclohexanone (1740-63-2)

Guidance literature:

With (lithium)2(CN)(methyl)2cuprate;

DOI:10.1021/ja00216a045

upstream raw materials:

cis-cyclooct-4-enone

cyclohexenone

Vinyl bromide

divinyltellane

Downstream raw materials:

1,4-dioxa-spiro[4.5]decane-7-carbaldehyde

Refernces

• 1、 Yamamoto, Keiji,Tsuji, Jiro. "PALLADIUM-CATALYZED ASYMMETRIC CYCLIZATION OF METHYL (E)-OXO-9-PHENOXY-7-NONENOATE AND ITS ANALOGS". . p. 3089 - 3092. Retrieved 1982.
• 2、 Yamamoto, Keiji,Deguchi, Ryoji,Ogimura, Yoshinobu,Tsuji, Jiro. "COMPLETE RETENTION OF CHIRALITY IN THE PALLADIUM CATALYZED CYCLIZATION OF METHYL (R)-3-OXO-7-METHOXYCARBONYLOXY)-8-NONENOATE". . p. 1657 - 1660. Retrieved 1984.
• 3、 Crandall et al.. "". . p. 1052. Retrieved 1967.
• 4、 Motherwell, William B.,Zuberi, Sheena. "Observations on the reductive ring opening reactions of alkylidenecyclopropyl ketones promoted by lithium in liquid ammonia". . p. 8789 - 8791. Retrieved 2007/10/03.