3,6-Dibromophenanthrene

Base Information

• Chemical Name: 3,6-Dibromophenanthrene
• CAS No.: 174735-02-5
• Molecular Formula: C14H8Br2
• Molecular Weight: 336.026
• Hs Code.: 2903999090
• DSSTox Substance ID: DTXSID70448591
• Nikkaji Number: J726.059H
• Wikidata: Q72464770
• Mol file: 174735-02-5.mol

Synonyms:3,6-dibromophenanthrene;174735-02-5;3,6-DIBROMO-PHENANTHRENE;Phenanthrene, 3,6-dibromo-;SCHEMBL1569370;DTXSID70448591;BCP18672;ZGA73502;MFCD08448064;AKOS016845753;BS-15657;SY266193;CS-0310763;FT-0697829;D82670;A846242

Chemical Property of 3,6-Dibromophenanthrene

Chemical Property:

• Melting Point: 188-191℃
• Boiling Point: 438.755 °C at 760 mmHg
• Flash Point: 256.192 °C
• PSA: 0.00000
• Density: 1.768 g/cm³
• LogP: 5.51800
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 335.89723
• Heavy Atom Count: 16
• Complexity: 227

Purity/Quality:

98% ^*data from raw suppliers

3,6-Dibromophenanthrene 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C=C(C=C2)Br)C3=C1C=CC(=C3)Br

Technology Process of 3,6-Dibromophenanthrene

There total 8 articles about 3,6-Dibromophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

(E)-4,4'-dibromostilbene (18869-30-2) → 3,6-dibromophenanthrene (174735-02-5)

Guidance literature:

With iodine; In tetrahydrofuran; toluene; for 16h; Irradiation;

DOI:10.3998/ark.5550190.0012.902

Reference yield: 97.0%

4,4'-dibromostilbene (2765-14-2,18869-30-2,23958-29-4,131899-14-4,131899-15-5) → 3,6-dibromophenanthrene (174735-02-5)

Guidance literature:

With tetrahydrofuran; iodine; In toluene; for 16h; Irradiation;

DOI:10.1246/bcsj.82.1182

Reference yield: 73.0%

3,6-dibromophenanthrene-9-carboxylic acid (860551-67-3) → 3,6-dibromophenanthrene (174735-02-5)

Guidance literature:

With quinoline; copper chromite; Heating;

DOI:10.1080/00304940609355993

upstream raw materials:

4,4'-dibromostilbene

3,6-Dibrom-9,10-dihydrophenanthren

(E)-4,4'-dibromostilbene

3,6-dibromophenanthrene-9-carboxylic acid

Downstream raw materials:

3-bromo-6-(p-methoxystyryl)phenanthrene

heptahelicene

3-(p-methoxystyryl)-6-styrylphenanthrene

distyryl-3,6-phenanthrene

Refernces

• 1、 Nakamura, Yosuke,Tsuihiji, Takeshi,Mita, Tadahiro,Minowa, Toshiyuki,Tobita, Seiji,Shizuka, Haruo,Nishimura, Jun. "Synthesis, structure, and electronic properties of syn-[2.2]phenanthrenophanes: First observation of their excimer fluorescence at high temperature". . p. 1006 - 1012. Retrieved 1996.
• 2、 Seo, Junseok,Park, So-Ra,Kim, Mina,Suh, Min Chul,Lee, Jihoon. "The role of electron-transporting Benzo[f]quinoline unit as an electron acceptor of new bipolar hosts for green PHOLEDs". . p. 959 - 966. Retrieved 2018/11/26.
• 3、 Guédouar, Habiba,Aloui, Faouzi,Beltifa, Asma,Ben Mansour, Hedi,Ben Hassine, Béchir. "Synthesis and characterization of phenanthrene derivatives with anticancer property against human colon and epithelial cancer cell lines". . p. 841 - 849. Retrieved 2017/06/20.