1-Methoxy-2-methylpropene

Base Information

• Chemical Name: 1-Methoxy-2-methylpropene
• CAS No.: 17574-84-4
• Molecular Formula: C5H10O
• Molecular Weight: 86.1338
• Hs Code.: 2909199090
• Mol file: 17574-84-4.mol

Synonyms:1-methoxy-2-methyl-propene;2-methyl-1-methoxypropene;1-Propene,1-methoxy-2-methyl;methyl 2-methylprop-1-en-1-yl ether;isobutenyl methyl ether;Ether,methyl 2-methylpropenyl;methoxy-2-methyl-1-propene;

Chemical Property of 1-Methoxy-2-methylpropene

Chemical Property:

• PSA: 9.23000
• LogP: 1.55650

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Methoxy-2-methylpropene

There total 6 articles about 1-Methoxy-2-methylpropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.5%

isobutyraldehyde dimethyl acetal (41632-89-7) → 1-methoxy-2-methylprop-1-ene (17574-84-4) + isobutyraldehyde (78-84-2)

Guidance literature:

With water; toluene-4-sulfonic acid; triethylamine; at 90 ℃; under 760.051 Torr; Product distribution / selectivity;

Reference yield:

Methyl-[2-methyl-prop-(E)-ylidene]-oxonium (113163-98-7) → methanol (67-56-1) + 1-methoxy-2-methylprop-1-ene (17574-84-4) + isobutylideneamine; protonated form + isobutyraldehyde (78-84-2)

Guidance literature:

With ammonia; Kinetics;

DOI:10.1039/b209955c

Reference yield:

cis-1-methoxy-2-methylcyclopropane (36024-53-0,36024-54-1) → methane (34557-54-5,27936-85-2) + cis-1-methoxybut-1-ene (10034-12-5) + trans-1-methoxy-butene (10034-13-6) + ethane (74-84-0) + 1-methoxy-2-methylprop-1-ene (17574-84-4) + trans-1-methoxy-2-methylcyclopropane (36024-53-0,36024-54-1)

Guidance literature:

In gas; at 416.7 ℃; under 28 Torr; Kinetics; Rate constant; Thermodynamic data; further temperatures; variation of initial pressure; further fragmentation products;

DOI:10.1039/f19858101415

upstream raw materials:

2-methyl-3,3-dimethoxy-1-propene

cis-1-methoxy-2-methylcyclopropane

trans-1-methoxy-2-methylcyclopropane

2-Methoxy-3,3-dimethyl-4,6-diphenyl-3,4-dihydro-2H-pyran

Downstream raw materials:

1-chloro-1-fluoro-3-methoxy-2,2-dimethyl-cyclopropane

6-methyl-6-p-tolylthio-5-methoxyhept-1-en-2-one

1-chloro-1-methoxy-2-methyl-2-(p-tolylsulfanyl)propane

4-Chloro-N-[1-methoxy-2-methyl-prop-(Z)-ylidene]-benzenesulfonamide

Refernces

• 1、 Bache-Andreassen, Lihn,Uggerud, Einar. "Trends in alkyl substituent effects on nucleophilic reactions of carbonyl compounds: Gas phase reactions between ammonia and R1R2COCH3+ oxonium ions". . p. 705 - 713. Retrieved 2007/10/03.