2,6-Dimethylphenyl phosphorodichloridate

Base Information

• Chemical Name: 2,6-Dimethylphenyl phosphorodichloridate
• CAS No.: 18350-98-6
• Molecular Formula: C8H9Cl2O2P
• Molecular Weight: 239.038
• DSSTox Substance ID: DTXSID00546195
• Nikkaji Number: J1.204.241H
• Wikidata: Q82423954
• Mol file: 18350-98-6.mol

Synonyms:phosphorodichloridic acid 2,6-dimethylphenyl ester;2,6-Dimethylphenyl phosphorodichloridate;18350-98-6;SCHEMBL3757859;DTXSID00546195;GJXLXCBGGOAWDI-UHFFFAOYSA-N;AKOS016025216;2,6-dimethylphenyl dichlorophosphoric acid

Chemical Property of 2,6-Dimethylphenyl phosphorodichloridate

Chemical Property:

• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 237.9717219
• Heavy Atom Count: 13
• Complexity: 206

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(C(=CC=C1)C)OP(=O)(Cl)Cl

Technology Process of 2,6-Dimethylphenyl phosphorodichloridate

There total 2 articles about 2,6-Dimethylphenyl phosphorodichloridate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.7%

2.6-dimethylphenol (576-26-1,25134-01-4) → 2,6-dimethylphenyl dichlorophosphoric acid (18350-98-6)

Guidance literature:

With calcium chloride; trichlorophosphate; for 15h; Heating / reflux;

Reference yield:

C8H9Cl3OP(1+)*Cl6Sb(1-) → 2,6-dimethylphenyl dichlorophosphoric acid (18350-98-6)

Guidance literature:

With water; In dichloromethane;

Reference yield: 69.0%

2,6-dimethylphenyl dichlorophosphoric acid (18350-98-6) + 2-hydroxy-5-chloro-aniline (95-85-2) → C20H17Cl2N2O3P (125790-34-3)

Guidance literature:

With triethylamine; In benzene; Heating;

upstream raw materials:

2.6-dimethylphenol

Downstream raw materials:

2,6-Dimethylphenyl phospholanate

6-(2,6-Dimethyl-phenoxy)-5,7-dioxa-6-phospha-dibenzo[a,c]cycloheptene 6-oxide

2,10-Dichloro-6-(2,6-dimethyl-phenoxy)-12H-5,7-dioxa-6-phospha-dibenzo[a,d]cyclooctene 6-oxide

C₂₉H₂₃O₄P

Refernces

• 1、 -. "PROCESS FOR PRODUCTION OF AMINATED PHOSPHORIC ACID ESTER COMPOUND, FLAME-RETARDANT RESIN, AND FLAME-RETARDANT RESIN COMPOSITION". Page/Page column 14. . Retrieved 2009/04/23.
• 2、 Gloede, Joerg,Waschke, Regine. "STABILE ADDUKTE BEI DER CHLORIERUNG VON 2,6-DIMETHYLPHENYLPHOSPHITEN". . p. 187 - 194. Retrieved 2007/10/02.