BIS(TRIMETHYLSILYL)SEBACATE

Base Information

• Chemical Name: BIS(TRIMETHYLSILYL)SEBACATE
• CAS No.: 18408-42-9
• Molecular Formula: C16H34O4Si2
• Molecular Weight: 346.615
• Mol file: 18408-42-9.mol

Synonyms:

Chemical Property of BIS(TRIMETHYLSILYL)SEBACATE

Chemical Property:

• Vapor Pressure: 6.12E-05mmHg at 25°C
• Refractive Index: 1.4342
• Boiling Point: 143°C 1mm
• Flash Point: 105°C

Purity/Quality:

98% ^*data from raw suppliers

BIS(TRIMETHYLSILYL)SEBACATE 97.00% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(TRIMETHYLSILYL)SEBACATE

There total 3 articles about BIS(TRIMETHYLSILYL)SEBACATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

dimethyl sebacate (106-79-6) + N,N-diethyl-1,1,1-trimethylsilanamine (996-50-9) → bis(trimethylsilyl) decanedioate (18408-42-9) + C14H28O4Si

Guidance literature:

With methyl iodide; In toluene; at 100 - 110 ℃; for 60h;

DOI:10.1016/0022-328X(95)05822-7

Reference yield:

1,10-decanedioic acid (111-20-6,26776-29-4) + N,O-Bis(trimethylsilyl)trifluoroacetamide (25561-30-2) → bis(trimethylsilyl) decanedioate (18408-42-9)

Guidance literature:

With pyridine; at 70 ℃; for 1h;

DOI:10.2478/s11532-011-0060-4

Reference yield:

→ bis(trimethylsilyl) decanedioate (18408-42-9)

Guidance literature:

/BRN= 1797803/;

DOI:10.1002/macp.1957.020240101

upstream raw materials:

dimethyl sebacate

N,N-diethyl-1,1,1-trimethylsilanamine

1,10-decanedioic acid

N,O-Bis(trimethylsilyl)trifluoroacetamide

Downstream raw materials:

1,10-decanedioic acid

Refernces

• 1、 Kotowska, Urszula,Isidorov, Valery A.. "Partition coefficients of ketones, phenols, aliphatic and aromatic acids, and esters in n-hexane/nitromethane". scheme or table. p. 813 - 824. Retrieved 2012/03/27.