4-Isopropylphenylmagnesium bromide

Base Information

• Chemical Name: 4-Isopropylphenylmagnesium bromide
• CAS No.: 18620-03-6
• Molecular Formula: C9H11BrMg
• Molecular Weight: 223.395
• Hs Code.: 2931900090
• European Community (EC) Number: 814-302-2
• Mol file: 18620-03-6.mol

Synonyms:18620-03-6;4-iso-propylphenylmagnesium bromide;magnesium;propan-2-ylbenzene;bromide;Magnesium, bromo[4-(1-methylethyl)phenyl]-;MFCD01319911;4-isopropylphenylmagnesium bromide;SCHEMBL661499;4-isopropylphenylmagnesiumbromide;4isopropylphenylmagnesium bromide;p-isopropylphenylmagnesium bromide;VLHDTCQJXYKEJT-UHFFFAOYSA-M;4-isopropylphenyl magnesium bromide;4-isopropyl-phenyl magnesium bromide;AKOS016017788;4-iso-Propylphenylmagnesium bromide, 0.5 M in THF;4-iso-Propylphenylmagnesium bromide, 0.5M 2-MeTHF;4-Isopropylphenylmagnesium bromide, 0.5M in 2-MeTHF;4-Isopropylphenylmagnesium bromide, 0.50 M in 2-MeTHF;4-iso-Propylphenylmagnesium bromide 0.5 M in Tetrahydrofuran

Chemical Property of 4-Isopropylphenylmagnesium bromide

Chemical Property:

• Flash Point: -17 °C
• PSA: 0.00000
• Density: 0.939 g/mL at 25 °C(lit.)
• LogP: 3.45580
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 221.98945
• Heavy Atom Count: 11
• Complexity: 162

Purity/Quality:

98.5% ^*data from raw suppliers

4-Isopropylphenylmagnesiumbromide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 11-19-36/37-40-37-34-14
• Safety Statements: 16-26-36/37-45-36/37/39-33-29-8

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1=CC=[C-]C=C1.[Mg+2].[Br-]

Technology Process of 4-Isopropylphenylmagnesium bromide

There total 3 articles about 4-Isopropylphenylmagnesium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-iso-propylbromobenzene (586-61-8) + magnesium (7439-95-4) → 4-isopropylphenylmagnesium bromide (18620-03-6)

Guidance literature:

In tetrahydrofuran;

Reference yield:

4-iso-propylbromobenzene (586-61-8) → 4-isopropylphenylmagnesium bromide (18620-03-6)

Guidance literature:

With magnesium; In tetrahydrofuran;

DOI:10.1002/adsc.201600535

Reference yield:

4-iso-propylbromobenzene (586-61-8) → 4,4' diisopropylbiphenyl (18970-30-4) + 4-isopropylphenylmagnesium bromide (18620-03-6)

Guidance literature:

With diethyl ether; bromine; magnesium; higher-melting form;

upstream raw materials:

4-iso-propylbromobenzene

magnesium

Downstream raw materials:

Trimethyl-(2-isopropylphenyl)silane

1-cyclohexyl-4-isopropylbenzene

1,4-bis(1-methylethyl)benzene

(+/-)-(4-isopropylphenyl)phenylmethanol

Refernces

• 1、 -. "BENZOQUINAZOLINE DERIVATIVES AND THEIR USE IN TREATING BONE DISORDERS". Page/Page column 97; 98-99. . Retrieved 2008/06/13.