Benzenemethanamine, N,a-diphenyl-

Base Information

• Chemical Name: Benzenemethanamine, N,a-diphenyl-
• CAS No.: 1865-12-9
• Molecular Formula: C19H17N
• Molecular Weight: 259.351
• Mol file: 1865-12-9.mol

Synonyms:

Chemical Property of Benzenemethanamine, N,a-diphenyl-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenemethanamine, N,a-diphenyl-

There total 84 articles about Benzenemethanamine, N,a-diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N-(diphenylmethylidene)phenylamine (574-45-8) → N-(diphenylmethyl)aniline (1865-12-9)

Guidance literature:

With Dimethylphenylsilane; gold; water; In acetonitrile; at 50 ℃; for 5h; chemoselective reaction;

DOI:10.1016/j.tet.2014.11.023

Reference yield: 99.0%

phenyllithium (591-51-5) + ethyl N-phenylformimidate (6780-49-0) → N-(diphenylmethyl)aniline (1865-12-9)

Guidance literature:

In diethyl ether; cyclohexane; at -30 - 0 ℃; for 1h;

DOI:10.1021/jo00287a028

Reference yield: 96.0%

1,1-Diphenylmethanol (91-01-0) + aniline (62-53-3) → N-(diphenylmethyl)aniline (1865-12-9)

Guidance literature:

With cesiumhydroxide monohydrate; oxygen; In 1,3,5-trimethyl-benzene; at 140 ℃; for 24h;

DOI:10.1002/ejoc.201500086

upstream raw materials:

syn-benzaldehyde oxime

diethyl ether

(Z)-benzaldehyde oxime

benzaldehyde-(O-methyl-seqcis-oxime )

Downstream raw materials:

N-benzhydryl-N-phenyl-acetamide

(2-aminophenyl)diphenylmethane

4-(diphenylmethyl)aniline

N-benzhydryl-4-chlorobutananilide

Refernces

• 1、 Murai, Kenichi,Kobayashi, Tetsuya,Miyoshi, Makoto,Fujioka, Hiromichi. "". . p. 2333 - 2337. Retrieved 2018.
• 2、 Bazkiaei, Adineh Rezaei,Wiseman, Michael,Findlater, Michael. "Iron-catalysed hydroboration of non-activated imines and nitriles: Kinetic and mechanistic studies". . p. 15284 - 15289. Retrieved 2021/05/19.
• 3、 Chang, Junbiao,Du, Yangxu,Hao, Wei,Hou, Jiao,Lu, Qing,Yu, Wenquan. "Iodine-mediated 1,2-aryl migration of primary benzhydryl amines". supporting information. p. 16223 - 16226. Retrieved 2021/09/22.