methyl(chloromethyl)hydrochlorosilane

Base Information

• Chemical Name: methyl(chloromethyl)hydrochlorosilane
• CAS No.: 20156-51-8
• Molecular Formula: C2H6Cl2Si
• Molecular Weight: 129.061
• Mol file: 20156-51-8.mol

Synonyms:Chlor-chlormethyl-methyl-silan;chloro(chloromethyl)(methyl)silane;chloromethylmethylchlorosilane;(Chlor)(chlormethyl)methylsilan;

Chemical Property of methyl(chloromethyl)hydrochlorosilane

Chemical Property:

• PSA: 0.00000
• LogP: 1.77510

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of methyl(chloromethyl)hydrochlorosilane

There total 3 articles about methyl(chloromethyl)hydrochlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

methyl(chloromethyl)dihydrosilane (18165-20-3) → methyl(chloromethyl)hydrochlorosilane (20156-51-8)

Guidance literature:

With succinic acid N-(chloromethyl)imide; In dichloromethane; at 20 ℃; for 1.5h;

DOI:10.1016/j.jorganchem.2007.01.035

Reference yield: 62.0%

methyl(chloromethyl)dihydrosilane (18165-20-3) + chloromethylmethyldichlorosilane (1558-33-4) → methyl(chloromethyl)hydrochlorosilane (20156-51-8)

Guidance literature:

With lithium borohydride; In N,N,N,N,N,N-hexamethylphosphoric triamide; at 20 ℃; for 0.5h;

DOI:10.1039/d0ra03536j

Reference yield:

chloromethylmethyldichlorosilane (1558-33-4) → methyl(chloromethyl)dihydrosilane (18165-20-3) + methyl(chloromethyl)hydrochlorosilane (20156-51-8)

Guidance literature:

With diphenylsilane; tetrabutyl-ammonium chloride; at 90 ℃; for 2h; Product distribution / selectivity;

upstream raw materials:

methyl(chloromethyl)dihydrosilane

chloromethylmethyldichlorosilane

Downstream raw materials:

dimethylmonochlorosilane

1,3,3-Trimethyl-1,3-disilapropan

2,5-disilahexane

1,1,3-trimethyl-1,3-disilacyclobutane

Refernces

• 1、 Chen, Yi,Li, Yongming,Xu, Caihong. "Facile preparation of hydrochlorosilane by alkali metal halide catalyzed Si-H/Si-Cl redistribution reaction". supporting information. . Retrieved 2020/09/21.
• 2、 Pestunovich, Vadim A.,Kirpichenko, Svetlana V.,Lazareva, Natal'ya F.,Albanov, Aleksander I.,Voronkov, Mikhail G.. "Pentacoordinate hydrochlorosilanes with lactamomethyl ligand". . p. 2160 - 2167. Retrieved 2007/10/03.