2-((Bis(dimethylamino)methylene)amino)-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium chloride

Base Information

• Chemical Name: 2-((Bis(dimethylamino)methylene)amino)-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium chloride
• CAS No.: 202282-59-5
• Molecular Formula: C₁₀H₂₂N₅*Cl
• Molecular Weight: 247.771
• European Community (EC) Number: 969-139-0
• Mol file: 202282-59-5.mol

Synonyms:202282-59-5;2-((Bis(dimethylamino)methylene)amino)-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium chloride;[dimethylamino-[(1,3-dimethylimidazolidin-2-ylidene)amino]methylidene]-dimethylazanium;chloride;2-{[bis(dimethylamino)methylidene]amino}-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium chloride;C10H22ClN5;SCHEMBL3598164;CIA28259;MFCD28977496;AKOS026674028;DS-9943;1H-Imidazolium,2-[[bis(dimethylamino)methylene]amino]-4,5-dihydro-1,3-dimethyl-,chloride;CS-0161683;C73825;A879768;2-((Bis(dimethylamino)methylene)amino)-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-iumchloride;2-((Bis(dimethylamino)methylene)amino)-1 pound not3-dimethyl-4 pound not5-dihydro-1H-imidazol-3-ium chloride

Chemical Property of 2-((Bis(dimethylamino)methylene)amino)-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium chloride

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 247.1563734
• Heavy Atom Count: 16
• Complexity: 263

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CN1CCN(C1=NC(=[N+](C)C)N(C)C)C.[Cl-]

Technology Process of 2-((Bis(dimethylamino)methylene)amino)-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium chloride

There total 3 articles about 2-((Bis(dimethylamino)methylene)amino)-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2-chloro-1,3-dimethylimidazolinium chloride (37091-73-9) + N,N,N',N'-tetramethylguanidine (80-70-6) → 1,3-dimethyl-2-(N',N',N,N-tetramethylguanidino)-4,5-dihydro-3H-imidazolium chloride (202282-59-5)

Guidance literature:

In tetrahydrofuran; dichloromethane; at 5 - 60 ℃; for 1.5h;

Reference yield: 94.0%

2,2-dichloro-1,3-dimethylimidazolidine (343927-22-0) + N,N,N',N'-tetramethylguanidine (80-70-6) → 1,3-dimethyl-2-(N',N',N,N-tetramethylguanidino)-4,5-dihydro-3H-imidazolium chloride (202282-59-5)

Guidance literature:

2,2-dichloro-1,3-dimethylimidazolidine; N,N,N',N'-tetramethylguanidine; In dichloromethane; for 2h;

With sodium methylate; In methanol; at 20 ℃; for 1h;

Reference yield:

1,3-dimethyl-2-imidazolidinone (80-73-9) + N,N,N',N'-tetramethylguanidine (80-70-6) → 1,3-dimethyl-2-(N',N',N,N-tetramethylguanidino)-4,5-dihydro-3H-imidazolium chloride (202282-59-5)

Guidance literature:

1,3-dimethyl-2-imidazolidinone; With phosgene; In toluene; at 40 ℃;

N,N,N',N'-tetramethylguanidine; In dichloromethane;

DOI:10.1016/j.jfluchem.2004.01.030

upstream raw materials:

1,3-dimethyl-2-imidazolidinone

N,N,N',N'-tetramethylguanidine

2,2-dichloro-1,3-dimethylimidazolidine

2-chloro-1,3-dimethylimidazolinium chloride

Refernces

• 1、 -. "BORATE-BASED BASE GENERATOR, AND BASE-REACTIVE COMPOSITION COMPRISING SUCH BASE GENERATOR". Paragraph 0502. . Retrieved 2016/12/12.
• 2、 Pleschke, Axel,Marhold,Schneider,Kolomeitsev,R?schenthaler. "Halex reactions of aromatic compounds catalysed by 2-azaallenium, carbophosphazenium, aminophosphonium and diphosphazenium salts: A comparative study". . p. 1031 - 1038. Retrieved 2007/10/03.