9,9-Diphenyl-9,10-dihydroacridine

Base Information

• Chemical Name: 9,9-Diphenyl-9,10-dihydroacridine
• CAS No.: 20474-15-1
• Molecular Formula: C25H19N
• Molecular Weight: 333.433
• European Community (EC) Number: 846-309-1
• Nikkaji Number: J3.543.672C
• Mol file: 20474-15-1.mol

Synonyms:9,9-Diphenyl-9,10-dihydroacridine;20474-15-1;9,9-diphenyl-10H-acridine;Acridine, 9,10-dihydro-9,9-diphenyl-;9,10-dihydro-9,9-diphenylacridine;MFCD28127357;9,9-diphenylacridan;SCHEMBL2453350;YSCK0644;HWTHOPMRUCFPBX-UHFFFAOYSA-N;AKOS027324203;DS-11477;SY234679;CS-0160454;D5332;F16814;A852511

Chemical Property of 9,9-Diphenyl-9,10-dihydroacridine

Chemical Property:

• Melting Point: 249.0 to 254.0 °C
• Boiling Point: 463.9±45.0 °C(Predicted)
• PKA: 1.15±0.40(Predicted)
• PSA: 12.03000
• Density: 1.154±0.06 g/cm3(Predicted)
• LogP: 6.26430
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• XLogP3: 6.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 333.151749610
• Heavy Atom Count: 26
• Complexity: 417

Purity/Quality:

99%, ^*data from raw suppliers

9,9-Diphenyl-9,10-dihydroacridine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2(C3=CC=CC=C3NC4=CC=CC=C42)C5=CC=CC=C5
• Description: 9,9-diphenyl-9,10-dihydroacridine is a dihydrouridine derivatives. It has several applications. It is ausefulraw materials of OLEDs, leading to OLEDs with excellent blue-light emission property, suitable energy levels, high mobility as well as good thermal stability. It can also be supplemented to platinum complexes, making it suitable for use as phosphorescent emitters or as delayed fluorescent and phosphorescent emitters.
• Uses: 9,9-Diphenyl-9,10-dihydroacridine is a reagent used in the synthesis and in the studies of acridan derivatives as antioxidants.

Technology Process of 9,9-Diphenyl-9,10-dihydroacridine

There total 14 articles about 9,9-Diphenyl-9,10-dihydroacridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

diphenyl(2-(phenylamino)phenyl)methanol (230627-85-7) → 9,10-dihydro-9,9-diphenyl acridine (20474-15-1)

Guidance literature:

With methanesulfonic acid; In tetrahydrofuran; toluene; at 20 ℃; for 8h;

Reference yield: 82.2%

→ 9,10-dihydro-9,9-diphenyl acridine (20474-15-1)

Guidance literature:

With phosphoric acid; at 20 ℃; for 12h;

Reference yield: 73.0%

Methyl N-phenylanthranilate (35708-19-1) + phenyllithium (591-51-5) → 9,10-dihydro-9,9-diphenyl acridine (20474-15-1)

Guidance literature:

Methyl N-phenylanthranilate; phenyllithium; In tetrahydrofuran; at -78 ℃; for 1h; Inert atmosphere;

With methyl bisulfate; In chloroform; for 1h; Reflux;

upstream raw materials:

diphenyl(2-(phenylamino)phenyl)methanol

Methyl N-phenylanthranilate

phenylmagnesium bromide

2-carbomethoxyaniline

Downstream raw materials:

10-acetyl-9,9-diphenyl-9,10-dihydro-acridine

9,9-diphenyl-10-methyl-9,10-dihydroacridine

9,9-diphenylacridin-3-one

Refernces

• 1、 -. "An electroluminescent compound and an electroluminescent device comprising the same". Paragraph 0273; 0292-0297; 0360; 0367-0372. . Retrieved 2020/12/16.
• 2、 -. "Heterocyclic compound and organic light emitting device including the same". . . Retrieved 2020/07/15.