Phenol, 2-[[[2,6-bis(1-methylethyl)phenyl]imino]methyl]-4,6-dichloro-

Base Information

• Chemical Name: Phenol, 2-[[[2,6-bis(1-methylethyl)phenyl]imino]methyl]-4,6-dichloro-
• CAS No.: 210882-40-9
• Molecular Formula: C₁₉H₂₁Cl₂NO
• Molecular Weight: 350.288
• Mol file: 210882-40-9.mol

Synonyms:

Chemical Property of Phenol, 2-[[[2,6-bis(1-methylethyl)phenyl]imino]methyl]-4,6-dichloro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenol, 2-[[[2,6-bis(1-methylethyl)phenyl]imino]methyl]-4,6-dichloro-

There total 1 articles about Phenol, 2-[[[2,6-bis(1-methylethyl)phenyl]imino]methyl]-4,6-dichloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) + 3,5-dichlorosalicyclaldehyde (90-60-8) → 4,6-dichloro-2-[[(2,6-diisopropylphenyl)imino]methyl]phenol (210882-40-9)

Guidance literature:

In methanol; for 0.5h;

DOI:10.1002/ejic.200801049

Reference yield: 96.8%

(N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) + 4,6-dichloro-2-[[(2,6-diisopropylphenyl)imino]methyl]phenol (210882-40-9) + 3,5-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonanee (63249-99-0) → [Pd(CH3)((2,4-Cl2C6H2OCHNC6H3-2,6-i-Pr)(3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)] (685867-70-3)

Guidance literature:

In methanol; toluene; byproducts: CH4, TMEDA; to a soln. of Pd-complex in toluene at -30°C was added phosphine in methanol, then salicylaldimine in toluene was added at -30°C, the soln. was stirred for 30 min, allowed to warm to room temp., stirredovernight (inert atm.); the solvent was removed in vac., cold pentane was added, ppt. was filtered, washed with cold (-78°C) pentane; elem. anal.;

DOI:10.1021/om0343059

Reference yield: 94.0%

bis(bis(trimethylsilyl)amido)zinc(II) + 4,6-dichloro-2-[[(2,6-diisopropylphenyl)imino]methyl]phenol (210882-40-9) → Zn(Cl2C6H2OCHNC6H3(C3H7)2)2 (331624-19-2)

Guidance literature:

In pentane; ligand was dissolved in pentane, soln. of Zn-complex in pentane was added; filtered, washed with pentane; elem. anal.;

DOI:10.1021/ic0006403

upstream raw materials:

2,6-diisopropylbenzenamine

3,5-dichlorosalicyclaldehyde

Downstream raw materials:

Zn(Cl₂C₆H₂OCHNC₆H₃(C₃H₇)2)2

Ni(CH₃)PN₃(CH₂)6C₆H₃(CH(CH₃)2)2NCHC₆H₂OCl₂

Pd(CH₃)PN₃(CH₂)6C₆H₃(CH(CH₃)2)2NCHC₆H₂OCl₂

[Pd(CH₃)((2,4-Cl₂C₆H₂OCHNC₆H₃-2,6-i-Pr)(3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)]

Refernces