METHANOL-14C (5-20 MCI/MMOL)

Base Information

• Chemical Name: METHANOL-14C (5-20 MCI/MMOL)
• CAS No.: 3046-50-2
• Molecular Formula: CH4 O
• Molecular Weight: 34.0312
• Mol file: 3046-50-2.mol

Synonyms:Methanol-14C(7CI)

Chemical Property of METHANOL-14C (5-20 MCI/MMOL)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 20.23000
• Density: 0.753g/cm³
• LogP: -0.39150
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

METHANOL[14C] 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,T,R
• Statements: 11-23/24/25-39/23/24/25
• Safety Statements: 7-16-36/37-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHANOL-14C (5-20 MCI/MMOL)

There total 4 articles about METHANOL-14C (5-20 MCI/MMOL) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N,N-dimethylaniline <14C> methiodide → methanol (67-56-1) + N,N-dimethyl-aniline (121-69-7,77733-26-7) + C7(14)CH11N + [14C]methanol (3046-50-2)

Guidance literature:

With potassium hydroxide; In toluene; at 150 ℃; kinetic isotope effect; other solvent;

Reference yield:

[14C]carbon dioxide (51-90-1) → [14C]methanol (3046-50-2)

Guidance literature:

With potassium hydroxide; hydrogen; copper(II) oxide; at 285 ℃; under 330978 - 338334 Torr; Reagens 4:Al₂O₃;

Reference yield:

lithium aluminium tetrahydride (16853-85-3) + [14C]carbon dioxide (51-90-1) → [14C]methanol (3046-50-2)

Guidance literature:

In not given; reduction of (14)CO2 with LiAlH4;;

upstream raw materials:

[14C]carbon dioxide

lithium aluminium tetrahydride

Downstream raw materials:

[14C]methyl iodide

[14C]formaldehyde

Refernces

• 1、 Matloubi, Hojatollah,Khalaj, Ali,Dowlatabadi, Reza,Shirvani, Gholamhossein. "Synthesis of N-(2,3-dihydro-1-[14C]methyl-2-oxo-5-phenyl-1H-1, 4-benzodiazepin-3-yl)-benzamide and N-(2,3-dihydro-1-[14C]methyl-2-oxo-5-phenyl-1H-1, 4-benzodiazepin-3-yl)-N-[14C]methyl-benzamide as novelcarbon-14 labelled CCK antagonists". . p. 347 - 350. Retrieved 2007/10/03.