Technology Process of Oxirane, 2-ethenyl-3-phenyl-, (2R,3R)-rel-
There total 32 articles about Oxirane, 2-ethenyl-3-phenyl-, (2R,3R)-rel- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
indium;
In
N,N-dimethyl acetamide;
at 0 ℃;
for 2h;
Yields of byproduct given;
DOI:10.1021/jo9816111
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 95 percent / m-CPBA; NaHCO3 / CH2Cl2 / 2 h / 20 °C
2.1: oxalyl chloride; DMSO; triethylamine / CH2Cl2 / -78 - 20 °C
3.1: KHMDS / toluene; tetrahydrofuran / -20 - 20 °C
3.2: toluene; tetrahydrofuran / -20 - 20 °C
With
oxalyl dichloride; potassium hexamethylsilazane; sodium hydrogencarbonate; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; dichloromethane; toluene;
2.1: Swern oxidation / 3.2: Wittig olefination;
DOI:10.1021/ol051653t
- Guidance literature:
-
With
potassium tert-butylate;
In
tetrahydrofuran;
at 0 ℃;
for 0.333333h;
Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/ja00347a042
