Cyclohexanol, 1-ethynyl-, 1-benzoate

Base Information Edit

Chemical Name:Cyclohexanol, 1-ethynyl-, 1-benzoate
CAS No.:23293-77-8
Molecular Formula:C15H16 O2
Molecular Weight:228.291
Hs Code.:
Mol file:23293-77-8.mol

Synonyms:Cyclohexanol,1-ethynyl-, benzoate (6CI,8CI,9CI); 1-Ethynylcyclohexyl benzoate; NSC 59917

Suppliers and Price of Cyclohexanol, 1-ethynyl-, 1-benzoate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 5 raw suppliers

Chemical Property of Cyclohexanol, 1-ethynyl-, 1-benzoate Edit

Chemical Property:

Vapor Pressure:0.000488mmHg at 25°C
Boiling Point:313.7°C at 760 mmHg
Flash Point:128.7°C
PSA：26.30000
Density:1.09g/cm³
LogP:3.17950

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Cyclohexanol, 1-ethynyl-, 1-benzoate

There total 3 articles about Cyclohexanol, 1-ethynyl-, 1-benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 98-88-4
benzoyl chloride

: 78-27-3
1-Ethynylcyclohexan-1-ol

: 23293-77-8
1-ethynylcyclohexyl benzoate

Guidance literature:: With pyridine; benzene;

Reference yield:

: 78-27-3
1-Ethynylcyclohexan-1-ol

: 93-97-0
benzoic acid anhydride

: 23293-77-8
1-ethynylcyclohexyl benzoate

Guidance literature:: 1-Ethynylcyclohexan-1-ol; benzoic acid anhydride; With triethylamine; In dichloromethane; at 0 ℃; for 0.25h; under 760.051 Torr;

With dmap; In dichloromethane; at 0 - 20 ℃; for 4h; under 760.051 Torr;
DOI:10.1002/adsc.201900314

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 23293-77-8
1-ethynylcyclohexyl benzoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.75 h / -78 °C / 760.05 Torr

1.2: 1.5 h / -78 °C / 760.05 Torr

2.1: potassium carbonate / methanol / 1 h / 760.05 Torr

3.1: triethylamine / dichloromethane / 0.25 h / 0 °C / 760.05 Torr

3.2: 4 h / 0 - 20 °C / 760.05 Torr

With n-butyllithium; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; hexane; dichloromethane;
DOI:10.1002/adsc.201900314