Allyl methyl sulfoxide

Base Information

• Chemical Name: Allyl methyl sulfoxide
• CAS No.: 21892-75-1
• Molecular Formula: C4H8OS
• Molecular Weight: 104.173
• DSSTox Substance ID: DTXSID301314249
• Nikkaji Number: J594.461I
• Mol file: 21892-75-1.mol

Synonyms:allyl methyl sulfoxide;3-methylsulfinylprop-1-ene;21892-75-1;1-Propene, 3-(methylsulfinyl)-;methyl allyl sulfoxide;3-methylsulinylprop-1-ene;3-methylsulfinyl-prop-1-ene;SCHEMBL30430;3-(methylsulfinyl)-1-propene;CHEBI:193605;DTXSID301314249

Chemical Property of Allyl methyl sulfoxide

Chemical Property:

• XLogP3: 0.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 104.02958605
• Heavy Atom Count: 6
• Complexity: 67.9

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CS(=O)CC=C

Technology Process of Allyl methyl sulfoxide

There total 1 articles about Allyl methyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

allylmethyl sulfide (10152-76-8) → allylmethylsulfoxide (21892-75-1) + allyl methyl sulfone (16215-14-8)

Guidance literature:

With tert.-butylhydroperoxide; [MoO3(2,2′-bipyridine)]_n; In decane; dichloromethane; at 20 ℃; for 1h;

DOI:10.1016/j.catcom.2017.09.022

Reference yield: 93.0%

allylmethylsulfoxide (21892-75-1) + 5-benzyloxy-1H-indole (1215-59-4) → C19H19NOS

Guidance literature:

With potassium phosphate; trifluoroacetic anhydride; In dichloromethane; at -78 - 20 ℃; for 1h; regioselective reaction;

DOI:10.1039/c7sc04723a

Reference yield: 92.0%

allylmethylsulfoxide (21892-75-1) → allyl methyl sulfone (16215-14-8)

Guidance literature:

With n-C₄F₉; perfluoro-cis-2,3-dialkyloxaziridine; n-C₃F₇; In chloroform; trichlorofluoromethane; at -20 ℃; for 0.25h;

DOI:10.1021/jo00089a020

upstream raw materials:

allylmethyl sulfide

Downstream raw materials:

allyl methyl sulfone

allylmethyl sulfide

methyl n-propyl sulfoxide

Refernces

• 1、 Cheng, Xiuyan,Zhang, Jianling,Liu, Lifei,Zheng, Lirong,Zhang, Fanyu,Duan, Ran,Sha, Yufei,Su, Zhuizhui,Xie, Fei. "Air atmospheric photocatalytic oxidation by ultrathin C,N-TiO2nanosheets". supporting information. p. 1165 - 1170. Retrieved 2021/02/26.
• 2、 Panda, Manas K.,Shaikh, Mobin M.,Ghosh, Prasenjit. "Controlled oxidation of organic sulfides to sulfoxides under ambient conditions by a series of titanium isopropoxide complexes using environmentally benign H2O2 as an oxidant". experimental part. p. 2428 - 2440. Retrieved 2010/06/18.