Boranamine, N,N-bis(1-methylethyl)-

Base Information

• Chemical Name: Boranamine, N,N-bis(1-methylethyl)-
• CAS No.: 22092-92-8
• Molecular Formula: C6H16BN
• Molecular Weight: 113.011
• Mol file: 22092-92-8.mol

Synonyms:

Chemical Property of Boranamine, N,N-bis(1-methylethyl)-

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Boranamine, N,N-bis(1-methylethyl)-

There total 10 articles about Boranamine, N,N-bis(1-methylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

isopropylamine borane (13240-38-5) + 1,3-bis-(2,6-diisopropylphenyl)-imidazol-2-ylidene (244187-81-3) → diisopropopylaminoborane (22092-92-8) + 1,3-bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene (888854-17-9)

Guidance literature:

In toluene; for 8h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3dt32988g

Reference yield:

diisopropylamine borane (55124-35-1) + cyclic(dimethylamino borane) dimer (23884-11-9) → dimethylamine borane (74-94-2) + diisopropopylaminoborane (22092-92-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 190h; Inert atmosphere;

DOI:10.1021/ja208752w

Reference yield:

diisopropylamine (108-18-9) → diisopropylamine borane (55124-35-1) + ((CH3)2CH)2NBHSC6F5 (1387442-12-7) + diisopropopylaminoborane (22092-92-8)

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: chloro(1,5-cyclooctadiene)rhodium(I) dimer / not given

chloro(1,5-cyclooctadiene)rhodium(I) dimer; In not given;

DOI:10.1021/ic3008188

upstream raw materials:

diisopropylamine borane

cyclic(dimethylamino borane) dimer

diisopropylamine

iPr₂NH*BH₂SC₆F₅

Downstream raw materials:

CH₃OC₆H₄CHCHBHN(CH(CH₃)2)2

N,N-diisopropyl-1-[B-(1E)-1-phenylethen-1-yl]-boranamine

C₅H₁₀CCHBHN(CH(CH₃)2)2

N,N,N',N'-tetraisopropylboranediamine

Refernces

• 1、 -. "METHODS OF PREPARATION OF AMINOBORANES AND APPLICATIONS FOR BORYLATION AND SUZUKI COUPLING". . . Retrieved 2022/03/02.
• 2、 Stubbs, Naomi E.,Jurca, Titel,Leitao, Erin M.,Woodall, Christopher H.,Manners, Ian. "Polyaminoborane main chain scission using N-heterocyclic carbenes; Formation of donor-stabilised monomeric aminoboranes". supporting information. p. 9098 - 9100. Retrieved 2013/09/24.