2,2-Dichloro-1-(4-phenoxyphenyl)ethanone

Base Information

• Chemical Name: 2,2-Dichloro-1-(4-phenoxyphenyl)ethanone
• CAS No.: 59867-68-4
• Deprecated CAS: 67775-25-1
• Molecular Formula: C14H10Cl2O2
• Molecular Weight: 281.138
• Hs Code.: 2914700090
• European Community (EC) Number: 261-966-9
• DSSTox Substance ID: DTXSID7069368
• Nikkaji Number: J32.016A
• Wikidata: Q72501002
• Mol file: 59867-68-4.mol

Synonyms:2,2-dichloro-1-(4-phenoxyphenyl)ethanone;59867-68-4;Ethanone, 2,2-dichloro-1-(4-phenoxyphenyl)-;2,2-Dichloro-1-(4-phenoxyphenyl)ethan-1-one;p-phenoxy-2,2-dichloroacetophenone;2,2-Dichloro-4-phenoxyacetophenone;EINECS 261-966-9;4-Phenoxy-2',2'-dichloroacetophenone;Sandoray-1000;SCHEMBL83789;DTXSID7069368;AMY6499;4-phenoxy-2,2-dichloroacetophenone;MFCD17976583;AKOS015888546;FT-0652974

Chemical Property of 2,2-Dichloro-1-(4-phenoxyphenyl)ethanone

Chemical Property:

• Melting Point: 67-69 °C
• Boiling Point: 389.7 °C at 760 mmHg
• Flash Point: 157.4 °C
• PSA: 26.30000
• Density: 1.309 g/cm³
• LogP: 4.55380
• Storage Temp.: 2-8°C
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 280.0057849
• Heavy Atom Count: 18
• Complexity: 267

Purity/Quality:

99% ^*data from raw suppliers

2,2-dichloro-1-(4-phenoxyphenyl)ethanone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OC2=CC=C(C=C2)C(=O)C(Cl)Cl
• Uses: 2,2-Dichloro-4-phenoxyacetophenone is a photoinitiator used in the color development in UV cured films.

Technology Process of 2,2-Dichloro-1-(4-phenoxyphenyl)ethanone

There total 2 articles about 2,2-Dichloro-1-(4-phenoxyphenyl)ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloroacethyl chloride (79-36-7) + diphenylether (101-84-8) → 2,2-dichloro-1-(4-phenoxyphenyl)ethan-1-one (59867-68-4)

Guidance literature:

With aluminium trichloride; In carbon disulfide;

DOI:10.1021/jm00341a025

Reference yield:

→ 2,2-dichloro-1-(4-phenoxyphenyl)ethan-1-one (59867-68-4)

Guidance literature:

Aus der Acetylverbindung mit Chlor;

Reference yield:

2,2-dichloro-1-(4-phenoxyphenyl)ethan-1-one (59867-68-4) → 4-phenoxyphenylglyoxal (70-97-3)

Guidance literature:

Multistep reaction; (i) NaOMe, MeOH, (ii) aq. HCl;

DOI:10.1021/jm00333a003

upstream raw materials:

dichloroacethyl chloride

diphenylether

Downstream raw materials:

4-phenoxyphenylglyoxal

Refernces