1,24-Tetracosanediol

Base Information

• Chemical Name: 1,24-Tetracosanediol
• CAS No.: 22513-82-2
• Molecular Formula: C24H50O2
• DSSTox Substance ID: DTXSID801315185
• Metabolomics Workbench ID: 44616
• Nikkaji Number: J1.101.511E
• Mol file: 22513-82-2.mol

Synonyms:1,24-Tetracosanediol;tetracosane-1,24-diol;22513-82-2;SCHEMBL484048;CHEBI:184670;DTXSID801315185;LMFA05000580

Chemical Property of 1,24-Tetracosanediol

Chemical Property:

• Vapor Pressure: 2.19E-11mmHg at 25°C
• XLogP3: 10
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 23
• Exact Mass: 370.381080833
• Heavy Atom Count: 26
• Complexity: 206

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(CCCCCCCCCCCCO)CCCCCCCCCCCO

Technology Process of 1,24-Tetracosanediol

There total 11 articles about 1,24-Tetracosanediol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tetracosa-1,23-diene (95746-47-7) → tetracosane-1,24-diol (22513-82-2)

Guidance literature:

tetracosa-1,23-diene; With diisoamyl borane; In tetrahydrofuran; at 20 ℃;

With sodium hydroxide; dihydrogen peroxide; In tetrahydrofuran; ethanol; at 50 ℃; for 3h; Further stages.;

DOI:10.1002/chem.200601866

Reference yield:

tetracosa-3,9,15,21-tetrayne-1,24-diol (95623-51-1) → tetracosane-1,24-diol (22513-82-2)

Guidance literature:

With hydrogen; platinum(IV) oxide; In ethyl acetate; Ambient temperature;

DOI:10.1021/jo01067a023

Reference yield:

eicosa-1,7,13,19-tetrayne-1,20-diyl-bis-magnesium bromide → tetracosane-1,24-diol (22513-82-2)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran / Heating

2: H₂ / PtO₂ / ethyl acetate / Ambient temperature

With hydrogen; platinum(IV) oxide; In tetrahydrofuran; ethyl acetate;

DOI:10.1021/jo01067a023

upstream raw materials:

tetracosanedioic acid dimethyl ester

methyl 24-acetoxytetracosanoate

tetracosa-3,9,15,21-tetrayne-1,24-diol

tetracosa-1,23-diene

Downstream raw materials:

1,24-tetracosanedi acid

30,30-Bis(11,11,11-triphenylundecyl)-29,31-dioxabicyclo<26.3.0>hentriacontan

Refernces

• 1、 Schill, Gottfried,Beckmann, Wolfgang,Vetter, Walter. "Statistical Syntheses of Rotaxanes". . p. 941 - 954. Retrieved 2007/10/02.