2-Methyl-2-decene

Base Information

• Chemical Name: 2-Methyl-2-decene
• CAS No.: 23381-92-2
• Molecular Formula: C11H22
• Molecular Weight: 154.296
• Hs Code.: 2901299090
• Mol file: 23381-92-2.mol

Synonyms:2-Methyl-dec-2-en;2-methyl-2-decene;2-methyl-dec-2-ene;2-Decene,2-methyl;

Chemical Property of 2-Methyl-2-decene

Chemical Property:

• Boiling Point: 191.8±3.0 °C(Predicted)
• PSA: 0.00000
• Density: 0.758±0.06 g/cm3(Predicted)
• LogP: 4.31310

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Methyl-2-decene

There total 3 articles about 2-Methyl-2-decene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

2-methyl-dec-1-ene (13151-27-4) → 2-methyldecane (6975-98-0) + 2-methyl-2-decene (23381-92-2)

Guidance literature:

With C₃₂H₄₆ClCoN₂O₂; phenylsilane; In benzene; at 60 ℃; for 3h; Inert atmosphere;

DOI:10.1021/ja5105602

Reference yield: 48.0%

benzylzinc chloride-lithium chloride complex + 2-methyl-2-bromodecane (502760-08-9) → 2-methyl-2-decene (23381-92-2) + 2-methyl-dec-1-ene (13151-27-4) + 2,2-dimethyl-1-phenyldecane (67969-62-4)

Guidance literature:

With silver trifluoromethanesulfonate; In acetonitrile; at 25 ℃; for 3h; Inert atmosphere;

DOI:10.1002/asia.201000068

Reference yield: 34.0%

n-butyl magnesium bromide (693-03-8) + t-butyl bromide (507-19-7) → 9,9,10,10-tetramethyloctadecane + 2-methyldecane (6975-98-0) + 2-methyl-2-decene (23381-92-2) + 2-methyl-dec-1-ene (13151-27-4)

Guidance literature:

With zirconocene dichloride;

DOI:10.1016/j.jorganchem.2006.12.029

upstream raw materials:

n-butyl magnesium bromide

t-butyl bromide

2-methyl-2-bromodecane

2-methyl-dec-1-ene

Downstream raw materials:

2-methyldecane-2,5-diol

(3-heptyl-6,7-dimethoxy-2,2-dimethyl-1,2-dihydronaphthalen-1-yl)(phenyl)methanone

2-methyldecane

6-oxoheptanoic acid

Refernces

• 1、 Mitamura, Yukihiro,Asada, Yoshihiro,Murakami, Kei,Someya, Hidenori,Yorimitsu, Hideki,Oshima, Koichiro. "Silver-catalyzed benzylation and allylation of tertiary alkyl bromides with organozinc reagents". experimental part. p. 1487 - 1493. Retrieved 2011/07/07.