3-Bromoperylene

Base Information

• Chemical Name: 3-Bromoperylene
• CAS No.: 23683-68-3
• Molecular Formula: C20H11Br
• Molecular Weight: 331.211
• Hs Code.: 2903399090
• DSSTox Substance ID: DTXSID00473295
• Nikkaji Number: J1.153.088E
• Wikidata: Q82302614
• Mol file: 23683-68-3.mol

Synonyms:3-bromoperylene;23683-68-3;Perylene, 3-bromo-;C20H11Br;SCHEMBL1187914;DTXSID00473295;GPBMCEWKAPSTOU-UHFFFAOYSA-N;MFCD12024274;AKOS016004428;CS-W021889;SB12588;AC-29446;AS-33288;A878163

Chemical Property of 3-Bromoperylene

Chemical Property:

• Melting Point: 245-246 °C
• Boiling Point: 512.0±19.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.560±0.06 g/cm3(Predicted)
• LogP: 6.49970
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 330.00441
• Heavy Atom Count: 21
• Complexity: 405

Purity/Quality:

99.5% ^*data from raw suppliers

3-Bromoperylene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC2=C3C(=C1)C4=C5C(=CC=C4)C(=CC=C5C3=CC=C2)Br
• Uses: 3-Bromoperylene can be useful in various organic synthesis.

Technology Process of 3-Bromoperylene

There total 5 articles about 3-Bromoperylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

PERYLENE (198-55-0) → 3-bromoperylene (23683-68-3)

Guidance literature:

With N-Bromosuccinimide; In tetrahydrofuran; at 20 ℃; for 40h; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.202102052

Reference yield: 100.0%

C30H34Si → 3-bromoperylene (23683-68-3)

Guidance literature:

With N-Bromosuccinimide; In dichloromethane; at 20 ℃;

DOI:10.1055/s-0037-1611085

Reference yield: 100.0%

C23H20Si → 3-bromoperylene (23683-68-3)

Guidance literature:

With N-Bromosuccinimide; In dichloromethane; at 20 ℃;

DOI:10.1055/s-0037-1611085

upstream raw materials:

PERYLENE

Downstream raw materials:

acetic acid 4-perylen-3-ylethynyl-benzyl ester

3-perylene-1'-α-D-2'-deoxyriboside-3',5'-di(p-toluoyl) ester

3-oxoperylene-1'-α-deoxyriboside-3',5'-di-O-(p-toluoyl) ester

4,4,5,5-tetramethyl-2-((perylene-3-yl)phenyl)-1,3,2-dioxaborolan

Refernces

• 1、 Torres, érica,Berberan-Santos, Mário Nuno,Brites, Maria Jo?o. "Synthesis, photophysical and electrochemical properties of perylene dyes". . p. 298 - 304. Retrieved 2015.
• 2、 Maeda, Hajime,Nanai, Yasuaki,Mizuno, Kazuhiko,Chiba, Junya,Takeshima, Sakiko,Inouye, Masahiko. "Photooxygenation of alkynylperylenes. Formation of dibenzo[jk,mn] phenanthrene-4,5-diones". . p. 8990 - 8993. Retrieved 2007.
• 3、 -. "Compound containing perylene and fluorobenzene as well as preparation method and application of compound". Paragraph 0010; 0034-0037; 0044-0047; 0054-0057. . Retrieved 2021/01/21.
• 4、 Wei, Yaxiong,Li, Yuanming,Li, Zefeng,Xu, Xinsheng,Cao, Xiaosong,Zhou, Xiaoguo,Yang, Chuluo. "Efficient Triplet–Triplet Annihilation Upconversion in Solution and Hydrogel Enabled by an S-T Absorption Os(II) Complex Dyad with an Elongated Triplet Lifetime". supporting information. p. 19001 - 19008. Retrieved 2021/12/17.