TEAL

Base Information

• Chemical Name: TEAL
• CAS No.: 2423-13-4
• Molecular Formula: C18H30O
• Molecular Weight: 262.436
• Mol file: 2423-13-4.mol

Synonyms:

Chemical Property of TEAL

Chemical Property:

Purity/Quality:

99.3% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of TEAL

There total 9 articles about TEAL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

linolenyl alcohol (506-44-5,2774-90-5) → (9Z,12Z,15Z)-9,12,15-Octadecatrien-1-al (2423-13-4)

Guidance literature:

With pyridinium chlorochromate;

DOI:10.1023/A:1012299021967

Reference yield:

(9Z,12Z,15Z)-octadeca-9-12,15-trienoic acid (463-40-1,1955-33-5,21661-10-9,21661-09-6,21661-13-2,21661-11-0) → (9Z,12Z,15Z)-9,12,15-Octadecatrien-1-al (2423-13-4)

Guidance literature:

Multi-step reaction with 2 steps

1: lithium aluminium tetrahydride / tetrahydrofuran / 3.25 h / 5 °C / Inert atmosphere; Cooling with ice

2: Dess-Martin periodane / dichloromethane / 25 °C / Inert atmosphere; Cooling with ice

With lithium aluminium tetrahydride; Dess-Martin periodane; In tetrahydrofuran; dichloromethane;

Reference yield:

methyl linolenate (301-00-8) → (9Z,12Z,15Z)-9,12,15-Octadecatrien-1-al (2423-13-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 99 percent / LiAlH₄

2: 98 percent / pyridinium chlorochromate

With lithium aluminium tetrahydride; pyridinium chlorochromate;

DOI:10.1023/A:1012299021967

upstream raw materials:

nonadeca-10c,13c,16c-triene-1,2-diol

linolenyl alcohol

methyl linolenate

1-acetoxy-nonadeca-10c,13c,16c-trien-2-one

Refernces

• 1、 Guan, Xingchao,Li, Yulong,Xie, Zhipeng,Xie, Zhixiang,Xu, Zhezhe. "Total Synthesis of Nominal ent-Chlorabietol B". . p. 5724 - 5732. Retrieved 2020.
• 2、 Hu, Jiefeng,Han, Xiaowei,Yuan, Yu,Shi, Zhuangzhi. "Stereoselective Synthesis of Z Fluoroalkenes through Copper-Catalyzed Hydrodefluorination of gem-Difluoroalkenes with Water". supporting information. p. 13342 - 13346. Retrieved 2017/10/17.