(Z)-7-Tetradecenoic acid

Base Information

• Chemical Name: (Z)-7-Tetradecenoic acid
• CAS No.: 2430-95-7
• Molecular Formula: C14H26O2
• Molecular Weight: 226.35500
• Hs Code.: 2916190090
• Mol file: 2430-95-7.mol

Synonyms:7-Tetradecenoic acid,(7Z);Tetradecen-(7c)-saeure-(1);Tetradec-7c-ensaeure;tetradec-7c-enoic acid;7-Tetradecenoic acid;(7Z)-tetradec-7-enic acid;(Z)-7-Tetradecenoic acid;

Chemical Property of (Z)-7-Tetradecenoic acid

Chemical Property:

• Melting Point: 4.0-5.0 °C
• Boiling Point: 344.7±21.0 °C(Predicted)
• PKA: 4.77±0.10(Predicted)
• PSA: 37.30000
• Density: 0.913±0.06 g/cm3(Predicted)
• LogP: 4.54810

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (Z)-7-Tetradecenoic acid

There total 18 articles about (Z)-7-Tetradecenoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(Z)-7-tetradecenal (65128-96-3) → (Z)-tetradec-7-enoic acid (2430-95-7)

Guidance literature:

With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In tert-butyl alcohol; at 20 ℃; for 3h;

DOI:10.1246/bcsj.76.1011

Reference yield: 93.0%

tetradec-7-ynoic acid (55182-86-0) → (Z)-tetradec-7-enoic acid (2430-95-7)

Guidance literature:

With quinoline; 5% Pd-CaCO3; hydrogen; In methanol; at 25 ℃; for 4h; under 760.051 Torr;

DOI:10.1002/anie.201611940

Reference yield: 66.0%

ethyl (Z)-tetradec-7-enoate (70680-14-7) → (Z)-tetradec-7-enoic acid (2430-95-7)

Guidance literature:

With potassium hydroxide; In ethanol; at 20 ℃; Inert atmosphere;

DOI:10.1021/acs.jnatprod.7b00757

upstream raw materials:

tetradec-7-ynoic acid

(Z)-tetradec-7-en-1-ol

(Z)-7-tetradecenal

2-(tetradec-7-yn-1-yloxy)tetrahydro-2H-pyran

Downstream raw materials:

(7R,8S)-methyl 7,8-bis((S)-2-methoxy-2-phenylacetoxy)tetradecanoate

(7S,8R)-methyl 7,8-bis((S)-2-methoxy-2-phenylacetoxy)tetradecanoate

sec-butyl (Z)-7-tetradecenoate

Refernces

• 1、 Subchev,Harizanov,Francke,Franke,Plass,Reckziegel,Schroeder,Pickett,Wadhams,Woodcock. "Sex pheromone of female vine bud moth, Theresimima ampellophaga comprises (2s)-butyl (7z)-tetradecenoate". . p. 1141 - 1151. Retrieved 1998.
• 2、 Bruns, Hilke,Herrmann, Jennifer,Müller, Rolf,Wang, Hui,Wagner D?bler, Irene,Schulz, Stefan. "Oxygenated N-Acyl Alanine Methyl Esters (NAMEs) from the Marine Bacterium Roseovarius tolerans EL-164". . p. 131 - 139. Retrieved 2018/02/07.
• 3、 Singh, Arti A.,Zulkifli, Siti N.A.,Meyns, Michaela,Hayes, Patricia Y.,De Voss, James J.. "Synthesis of highly enantioenriched hydroxy- and dihydroxy-fatty esters: Substrate precursors for cytochrome P450BioI". experimental part. p. 1709 - 1719. Retrieved 2012/02/06.