Thioacetic acid S-octyl ester

Base Information

• Chemical Name: Thioacetic acid S-octyl ester
• CAS No.: 2432-34-0
• Molecular Formula: C10H20OS
• Molecular Weight: 188.334
• Hs Code.: 2930909090
• Mol file: 2432-34-0.mol

Synonyms:octyl thioacetate;1-acetylthiooctane;Thioessigsaeure-S-octylester;thioacetic acid S-octyl ester;

Chemical Property of Thioacetic acid S-octyl ester

Chemical Property:

• PSA: 42.37000
• LogP: 3.62660

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thioacetic acid S-octyl ester

There total 32 articles about Thioacetic acid S-octyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-Iodooctane (629-27-6) + potassium thioacetate (10387-40-3) → S-octyl thioacetate (2432-34-0)

Guidance literature:

With silica gel; In benzene; at 80 ℃; for 3h;

DOI:10.1081/SCC-120025193

Reference yield: 95.0%

1-bromo-octane (111-83-1) + sodium thioacetate (34832-35-4) → S-octyl thioacetate (2432-34-0)

Guidance literature:

With polyethylene glycol 400; at 20 ℃; for 4h;

DOI:10.1080/00397910600941380

Reference yield: 94.0%

acetic anhydride (108-24-7) + octyl 2-(trimethylsilyl)ethyl sulfide (222735-64-0) → S-octyl thioacetate (2432-34-0)

Guidance literature:

With boron trifluoride diethyl etherate; In dichloromethane; for 0.3h;

DOI:10.1016/S0040-4039(99)00016-7

upstream raw materials:

thioacetic acid

oct-1-ene

tiolacetic acid

2-methyl-1,3-oxathiolane

Downstream raw materials:

Octanethiol

dioctyl disulfide

Refernces

• 1、 Jain, Isha,Sharma, Ramandeep,Malik, Payal. "Manganese-mediated acetylation of alcohols, phenols, thiols, and amines utilizing acetic anhydride". supporting information. p. 2952 - 2960. Retrieved 2019/09/13.
• 2、 Olivito,Costanzo,Di Gioia,Nardi,Oliverio,Procopio. "Efficient synthesis of organic thioacetates in water". supporting information. p. 7753 - 7759. Retrieved 2018/11/02.