Butyl(chloro)diphenylsilane

Base Information

• Chemical Name: Butyl(chloro)diphenylsilane
• CAS No.: 24635-48-1
• Molecular Formula: C16H19ClSi
• Molecular Weight: 274.86100
• DSSTox Substance ID: DTXSID90503994
• Wikidata: Q82358166
• Mol file: 24635-48-1.mol

Synonyms:BUTYL(CHLORO)DIPHENYLSILANE;24635-48-1;SCHEMBL436840;DTXSID90503994

Chemical Property of Butyl(chloro)diphenylsilane

Chemical Property:

• Boiling Point: 163-165 °C(Press: 1 Torr)
• PSA: 0.00000
• Density: 1.04±0.1 g/cm3(Predicted)
• LogP: 3.78520
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 274.0944548
• Heavy Atom Count: 18
• Complexity: 211

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCC[Si](C1=CC=CC=C1)(C2=CC=CC=C2)Cl

Technology Process of Butyl(chloro)diphenylsilane

There total 2 articles about Butyl(chloro)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + diphenylsilyl dichloride (80-10-4) → chloro(butyl)diphenylsilane (24635-48-1)

Guidance literature:

In pentane; for 1h; Yield given; Heating;

Reference yield:

→ chloro(butyl)diphenylsilane (24635-48-1)

Guidance literature:

(C6H5)2SiCl2, n-Butyllithium;

DOI:10.1021/bi00600a021

Reference yield: 94.0%

chloro(butyl)diphenylsilane (24635-48-1) + (S)-4-benzyloxy-1,2-butanediol (71998-69-1,86990-91-2,104973-80-0,69985-32-6) → (S)-4-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-butan-2-ol (113522-78-4)

Guidance literature:

In pyridine; at 0 ℃; for 4h;

DOI:10.1016/S0040-4039(00)96294-4

upstream raw materials:

n-butyllithium

diphenylsilyl dichloride

Downstream raw materials:

(S)-4-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-butan-2-ol

(S)-4-Benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-butyronitrile

(S)-4-Benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-butylideneamine

(R)-4-Benzyloxy-2-(tert-butyl-diphenyl-silanyloxymethyl)-butyraldehyde

Refernces

• 1、 Nadvornik, Milan,Handlir, Karel,Holecek, Jaroslav,Klikorka, Jiri,Lycka, Antonin. "Synthese von einigen Alkyldiphenylchlorsilanen und Alkyldiphenylsilanolen". . p. 343. Retrieved 2007/10/02.