Methyl 11-hydroxyundecanoate

Base Information

• Chemical Name: Methyl 11-hydroxyundecanoate
• CAS No.: 24724-07-0
• Molecular Formula: C12H24O3
• Molecular Weight: 216.321
• Hs Code.: 2918199090
• Mol file: 24724-07-0.mol

Synonyms:ω-Oxy-undecylsaeure-methylester;methyl 11-hydroxyundecanoate;11-Hydroxy-undecansaeure-methylester;11-hydroxy-undecanoic acid methyl ester;Undecanoic acid, 11-hydroxy-, methyl ester;11-hydroxy methylundecanoate;

Chemical Property of Methyl 11-hydroxyundecanoate

Chemical Property:

• Melting Point: 27.5°C
• Refractive Index: 1.4410 (estimate)
• Boiling Point: 296.74°C (rough estimate)
• PSA: 46.53000
• Density: 0.9542
• LogP: 2.66260

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Methyl 11-hydroxyundecanoate

There total 2 articles about Methyl 11-hydroxyundecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + Methyl 10-undecenoate (111-81-9) → undecane-1,11-diol (765-04-8) + methyl 11-hydroxyundecanoate (24724-07-0)

Guidance literature:

und Erwaermen des Reaktionsprodukts mit wss.Wasserstoffperoxid und aethanol.Natronlauge;

Reference yield:

Methyl 10-undecenoate (111-81-9) → methyl undecanoate (1731-86-8) + methyl 11-hydroxyundecanoate (24724-07-0)

Guidance literature:

With sodium tetrahydroborate; water; dihydrogen peroxide; sodium acetate; copper(l) chloride; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, 25 deg C, 24 h, 2.) 0 deg C;

Reference yield: 91.0%

methyl 11-hydroxyundecanoate (24724-07-0) + dichloro(mesityl)phosphane (6781-96-0) → dimethyl 11,11'-(mesitylphosphinediyl)bis(oxy)diundecanoate

Guidance literature:

With triethylamine; In toluene; at 20 ℃; for 2h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.chemphyslip.2013.06.002

upstream raw materials:

Methyl 10-undecenoate

tetrahydrofuran

Downstream raw materials:

11-hydroxyundecanoic acid

11-bromo-undecanoic acid methyl ester

Methyl 11-tert-Butyldiphenylsilyloxyundecanoate

11-cyanoundecanoic acid methyl ester

Refernces