(1-Methylpentyl) hydroperoxide

Base Information

• Chemical Name: (1-Methylpentyl) hydroperoxide
• CAS No.: 24254-55-5
• Molecular Formula: C6H14 O2
• Molecular Weight: 118.176
• Hs Code.: 2909600000
• Mol file: 24254-55-5.mol

Synonyms:2-Hexylhydroperoxide; 2-Hydroperoxyhexane

Chemical Property of (1-Methylpentyl) hydroperoxide

Chemical Property:

• Vapor Pressure: 0.362mmHg at 25°C
• Boiling Point: 175°C at 760 mmHg
• PKA: 12.76±0.10(Predicted)
• Flash Point: 59.6°C
• PSA: 29.46000
• Density: 0.896g/cm³
• LogP: 2.05470

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1-Methylpentyl) hydroperoxide

There total 4 articles about (1-Methylpentyl) hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hexane (110-54-3) → hydroperoxide, 1-methylpentyl (24254-55-5) + n-hexan-3-ol (623-37-0) + n-hexan-2-ol (626-93-7) + hydroperoxide, 1-ethylbutyl (24254-56-6) + n-hexan-2-one (591-78-6) + n-hexan-3-one (589-38-8) + hexanal (66-25-1)

Guidance literature:

With dichloro[N,N'-bis(2-pyridinealdehyde)cyclohexanodiminate]iron(II); dihydrogen peroxide; nitric acid; In acetonitrile; at 20 ℃; for 3h; under 760.051 Torr; Overall yield = 86.4 %; Catalytic behavior;

DOI:10.1016/j.cattod.2012.07.043

Reference yield:

hexane (110-54-3) → hydroperoxide, 1-methylpentyl (24254-55-5) + n-hexan-3-ol (623-37-0) + n-hexan-2-ol (626-93-7) + hydroperoxide, 1-ethylbutyl (24254-56-6) + n-hexan-2-one (591-78-6) + n-hexan-3-one (589-38-8)

Guidance literature:

With 2,5-Dimethyl-1,4-benzoquinone; oxygen; In neat liquid; at 24.84 ℃; Quantum yield; Kinetics; Irradiation; Green chemistry;

DOI:10.1039/c6pp00102e

Reference yield:

hexane (110-54-3) → hydroperoxide, 1-methylpentyl (24254-55-5) + n-hexan-2-ol (626-93-7)

Guidance literature:

hexane; With {Copper(I)-tris((2-pyridyl)methyl)amine(CH₃CN)} hexafluorophosphate; dihydrogen peroxide; In water; acetonitrile; at 20 ℃; for 6h;

With triphenylphosphine; for 0.333333h; Reagent/catalyst; Cooling with ice;

DOI:10.1002/anie.201607216

upstream raw materials:

hexane

Downstream raw materials:

2,5-dimethyltetrahydrofuran

n-hexan-2-ol

n-hexan-2-one

octanol

Refernces

• 1、 Ohkubo, Kei,Hirose, Kensaku,Fukuzumi, Shunichi. "Solvent-Free Photooxidation of Alkanes by Dioxygen with 2,3-Dichloro-5,6-dicyano-p-benzoquinone via Photoinduced Electron Transfer". supporting information. p. 2255 - 2259. Retrieved 2016/08/30.
• 2、 Silva, Ana Rosa,Mour?o, Teresa,Rocha, Jo?o. "Oxidation of cyclohexane by transition-metal complexes with biomimetic ligands". . p. 81 - 86. Retrieved 2013/08/24.