N,N-Dimethylaminomethyltributylstannane

Base Information

• Chemical Name: N,N-Dimethylaminomethyltributylstannane
• CAS No.: 26285-62-1
• Molecular Formula: C15H35NSn
• Molecular Weight: 348.16
• Mol file: 26285-62-1.mol

Synonyms:tert.-Butyldimethylaminomethylperoxid;dimethylaminomethyltributyltin;tert-Butylperoxymethyldimethylamin;dimethylaminomethyltributyletain;tert.-Butyldioxy-trimethylamin;(N,N-Dimethylaminomethyl)-tributylzinn;Methanamine,1-[(1,1-dimethylethyl)dioxy]-N,N-dimethyl;Dimethylaminomethyl-tert.butylperoxid;

Chemical Property of N,N-Dimethylaminomethyltributylstannane

Chemical Property:

• Vapor Pressure: 0.000241mmHg at 25°C
• Boiling Point: 324.7oC at 760 mmHg
• Flash Point: 150.2oC
• PSA: 3.24000
• LogP: 4.00040

Purity/Quality:

96+% ^*data from raw suppliers

N,N-DIMETHYLAMINOMETHYLTRIBUTYLSTANNANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N-Dimethylaminomethyltributylstannane

There total 6 articles about N,N-Dimethylaminomethyltributylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

isopropylmagnesium chloride (1068-55-9) + tri-n-butyl-tin hydride (688-73-3) + N,N-dimethyl(methylene)ammonium chloride (30354-18-8) → dimethylaminomethyltributyltin (26285-62-1)

Guidance literature:

In diethyl ether; byproducts: propane, MgCl2; dry atmosphere; addn. of one equiv. of ethereal soln. of C3H7MgCl to Bu3SnH (0.125 mol); exothermic reaction; white soln. refluxed (2 h); addn. of immonium salt (0.1 mol); stirring for 2 h at room temp.; hydrolysis at 0 ° C;; extn. with ether, evapn., distn.,;

DOI:10.1016/S0022-328X(00)99388-4

Reference yield: 78.0%

isopropylmagnesium chloride (1068-55-9) + tri-n-butyl-tin hydride (688-73-3) + eschenmoser's salt (33797-51-2) → dimethylaminomethyltributyltin (26285-62-1)

Guidance literature:

In diethyl ether; byproducts: propane, MgClI; dry atmosphere; addn. of one equiv. of ethereal soln. of C3H7MgCl to Bu3SnH (0.125 mol); exothermic reaction; white soln. refluxed (2 h); addn. of immonium salt (0.1 mol); stirring for 2 h at room temp.; hydrolysis at 0 ° C;; extn. with ether, evapn., distn.,;

DOI:10.1016/S0022-328X(00)99388-4

Reference yield: 75.0%

tri-n-butyltin lithium (4226-01-1) + dimethylamino-methanesulfonic acid ; sodium salt → dimethylaminomethyltributyltin (26285-62-1)

Guidance literature:

In tetrahydrofuran;

DOI:10.1021/ja00745a034

upstream raw materials:

(dimethylaminomethyl)trichlorostannane

tri-n-butyltin lithium

dimethyl<(phenylthio)methyl>amine

isopropylmagnesium chloride

Downstream raw materials:

2-dimethylamino-1-phenylethanol

tetra-n-butyltin(IV)

1-(3, 4-dimethoxyphenyl)-2-dimethylaminoethanol

amylocaine

Refernces

• 1、 Tzschach, A.,Uhlig, W.,Kellner, K.. "SYNTHESE UND REAKTIONSVERHALTEN VON (DIALKYLAMINOMETHYL)CHLORSILANEN UND -STANNANEN". . p. 17 - 24. Retrieved 2007/10/02.