1,1,2,2,3,3,4,4,5,5,6,6,7-Tridecafluoroheptane

Base Information

• Chemical Name: 1,1,2,2,3,3,4,4,5,5,6,6,7-Tridecafluoroheptane
• CAS No.: 2708-11-4
• Molecular Formula: C7H3F13
• Molecular Weight: 334.08
• DSSTox Substance ID: DTXSID40507664
• Mol file: 2708-11-4.mol

Synonyms:1,1,2,2,3,3,4,4,5,5,6,6,7-Tridecafluoroheptane;2708-11-4;SCHEMBL9001859;DTXSID40507664;NEPJJOZUUYURBJ-UHFFFAOYSA-N;VVNJKLZRNLENCO-UHFFFAOYSA-N

Chemical Property of 1,1,2,2,3,3,4,4,5,5,6,6,7-Tridecafluoroheptane

Chemical Property:

• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 13
• Rotatable Bond Count: 6
• Exact Mass: 334.0027162
• Heavy Atom Count: 20
• Complexity: 343

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(C(C(C(C(C(C(F)F)(F)F)(F)F)(F)F)(F)F)(F)F)F

Technology Process of 1,1,2,2,3,3,4,4,5,5,6,6,7-Tridecafluoroheptane

There total 7 articles about 1,1,2,2,3,3,4,4,5,5,6,6,7-Tridecafluoroheptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

α,α,ω-trihydroperfluoroheptyloxytrifluorosulfurane (78491-62-0) → 1,1,2,2,3,3,4,4,5,5,6,6,7-tridecafluoroheptane (2708-11-4)

Guidance literature:

With hydrogen fluoride; at 25 ℃; for 1h;

Reference yield: 89.0%

phenyl-1,1,7-trihydroperfluoroheptyliodonium fluoroborate → iodobenzene (591-50-4) + 1,1,2,2,3,3,4,4,5,5,6,6,7-tridecafluoroheptane (2708-11-4)

Guidance literature:

at 150 - 160 ℃; for 4h; sealed tube;

Reference yield:

trimethyl-(1H,1H,7H-dodecafluoroheptyloxy)silane (56002-71-2) → 1,1,2,2,3,3,4,4,5,5,6,6,7-tridecafluoroheptane (2708-11-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 99 percent / diethyl ether / 1.) 0 deg C - 5 deg C, 10 min; 2.) 20 deg C, 30 min.

2: 4.45 g / 0.05 - 0.08 Torr / the bath temperature gradually raised to 90 deg C

In diethyl ether;

upstream raw materials:

α,α,ω-trihydroperfluoroheptyloxytrifluorosulfurane

C₁₁H₁₃F₁₄NOS

trimethyl-(1H,1H,7H-dodecafluoroheptyloxy)silane

Refernces

• 1、 Markovskii, L. N.,Bobkova, L. S.,Yaremenko, V. V.,Pashinnik, V. E.. "REACTION OF 1,1,7-TRIHYDRODODECAFLUOROHEPTYLOXYTRIFLUOROSULFURANE WITH ACIDS". . p. 1444 - 1447. Retrieved 2007/10/02.