ISOPROPYLTRICHLOROSILANE

Base Information

• Chemical Name: ISOPROPYLTRICHLOROSILANE
• CAS No.: 4170-46-1
• Molecular Formula: C3H7 Cl3 Si
• Molecular Weight: 177.533
• Hs Code.: 2931900090
• Mol file: 4170-46-1.mol

Synonyms:Silane,trichloroisopropyl- (6CI,7CI,8CI); 1,1,1-Trichloro-2-methyl-1-silapropane;Isopropyltrichlorosilane; Trichloroisopropylsilane

Chemical Property of ISOPROPYLTRICHLOROSILANE

Chemical Property:

• Vapor Pressure: 21.7mmHg at 25°C
• Melting Point: -87.7°C
• Refractive Index: 1.4319
• Boiling Point: 116.4°Cat760mmHg
• Flash Point: 31.2°C
• PSA: 0.00000
• Density: 1.196g/cm³
• LogP: 3.05170

Purity/Quality:

98%,99%, ^*data from raw suppliers

Isopropyltrichlorosilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ISOPROPYLTRICHLOROSILANE

There total 14 articles about ISOPROPYLTRICHLOROSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

→ 1,1,1-trichloro-2-methyl-1-silapropane (4170-46-1)

Guidance literature:

Reference yield: 44.0%

isopropyl chloride (75-29-6) → 1,1,1-trichloro-2-methyl-1-silapropane (4170-46-1)

Guidance literature:

isopropyl chloride; With magnesium; In diethyl ether; at 20 ℃; for 4h; Reflux;

With tetrachlorosilane; In diethyl ether; for 12h; Reflux;

DOI:10.1002/ejoc.200800107

Reference yield: 42.4%

isopropyl chloride (75-29-6) + (dichlorosilylmethyl)trichlorosilane (18171-02-3) → 1,1,3,3,5,5-hexachloro-1,3,5-trisilacyclohexane (16538-69-5) + 1,1,1-trichloro-2-methyl-1-silapropane (4170-46-1) + 1,1,1,3,3,5,5,5-octachloro-1,3,5-trisilapentane (16538-67-3)

Guidance literature:

tetra-n-butylphosphonium chloride; at 180 ℃; for 13h; Inert atmosphere;

upstream raw materials:

isopropyl chloride

isopropylmagnesium chloride

isopropylmagnesium bromide

i-prSi(NCS)3

Downstream raw materials:

Bis-(o-ethoxyphenyl)-chlorisopropylsilan

Bis-(o-butoxyphenyl)-chlorisopropylsilan

Chlorisopropylbis-(o-propoxyphenyl)-silan

Chlorbis-(isobutoxyphenyl)-isopropylsilan

Refernces

• 1、 Hairston,T.J.,O'Brien,D.H.. "-". . p. 79 - 92. Retrieved 1971.
• 2、 Rendler, Sebastian,Froehlich, Roland,Keller, Manfred,Oestreich, Martin. "Enantio- and diastereotopos differentiation in the palladium(II)-catalyzed hydrosilylation of bicyclo[2.2.1]alkene scaffolds with silicon-stereogenic silanes". supporting information; experimental part. p. 2582 - 2591. Retrieved 2009/04/05.
• 3、 -. "Process for preparing organochlorosilanes by dehydrohalogenative coupling reaction of alkyl halides with chlorosilanes". . . Retrieved 2008/06/13.