Technology Process of Germane, triethylphenyl-
There total 11 articles about Germane, triethylphenyl- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
phenylmagnesium bromide;
In
diethyl ether; benzene;
addn. of the germane in benzene to the freshly prepd. Grignard compoundin ether; refluxing for 3.5 h;; hydrolized with ice and dilute hydrochloric acid; chromy. (silica gel, hexane); fractional distn.;;
DOI:10.1246/bcsj.59.2807
- Guidance literature:
-
In
methanol;
at room temp. 4 days; hydrolysis of reaction mixture; detected by GC-MS and NMR;
DOI:10.1246/cl.2001.1086
- Guidance literature:
-
With
magnesium;
In
tetrahydrofuran;
byproducts: MgBr2; Sonication; the mixt. of magnesium, germane and halogen-compound in THF was sonicated for 2 h (inert atm.); the mixt. was washed with satd. soln. of NaCl, extd. with diethyl ether,the organic layer was dried over MgSO4, the solvent was removed under r educed pressure, column chromy. (petroleum ether-diethyl ether 95/5);
DOI:10.1016/S0022-328X(03)00053-6
