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Sodium 1-naphthalenesulfonate

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Name

Sodium 1-naphthalenesulfonate

EINECS 204-976-0
CAS No. 130-14-3 Density 1.423g/cm3
PSA 65.58000 LogP 2.82470
Solubility Soluble in water. Melting Point 299-301 °C
Formula C10H7NaO3S Boiling Point N/A
Molecular Weight 230.22 Flash Point N/A
Transport Information N/A Appearance N/A
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 130-14-3 (Sodium 1-naphthalenesulfonate) Hazard Symbols IrritantXi
Synonyms

1-Naphthalenesulfonicacid, sodium salt (8CI,9CI);Alpha salt;Sodium1-naphthylsulfonate;Sodium a-naphthalenesulfonate;Sodium a-naphthalenesulfonic acid;Sodium a-naphthylsulfonate;a-Naphthalenesulfonic acid sodium salt;

Article Data 5

Sodium 1-naphthalenesulfonate Synthetic route

81292-93-5

Naphthalinsulfonsaeure-trimethylsilylester

130-14-3

sodium 1-naphthalenesulfonate

Conditions
ConditionsYield
With sodium hydrogencarbonate In tetrachloromethane for 0.333333h; Yield given;
130-14-3

sodium 1-naphthalenesulfonate

85-46-1

1-Naphthalenesulfonyl chloride

Conditions
ConditionsYield
With trichlorophosphate In sulfolane; acetonitrile at 68 - 72℃; for 0.666667h;94%
With phosphorus pentachloride
With phosphorus pentachloride at 125℃; aus bei 180grad getrocknetem Edukt1 und Behandeln nach dem Abkuehlen mit Eis und mit Wasser;
With chlorine-triphenylphosphine In acetonitrile for 15h; Ambient temperature;

(1R,2R,4S)-2-(3-chlorophenyl)-1-(4-chlorophenyl)-4-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)-4-methylhept-6-en-1-ol

130-14-3

sodium 1-naphthalenesulfonate

108-88-3

toluene

7143-01-3

Methanesulfonic anhydride

A

C27H33Cl2NO4S

B

C33H37Cl2NO4S

C

C26H30Cl2NO(1+)*C10H7O3S(1-)*0.5C7H8

Conditions
ConditionsYield
Stage #1: (1R,2R,4S)-2-(3-chlorophenyl)-1-(4-chlorophenyl)-4-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)-4-methylhept-6-en-1-ol; toluene; Methanesulfonic anhydride With 2,6-dimethylpyridine at 75℃; for 12h;
Stage #2: With sulfuric acid In dichloromethane; water at 20℃; for 0.5h;
Stage #3: sodium 1-naphthalenesulfonate In dichloromethane; water
A n/a
B n/a
C 90%
290-37-9

1,4-pyrazine

130-14-3

sodium 1-naphthalenesulfonate

silver nitrate

[Ag(1-naphthalenesulfonate)(pyrazine)]*H2O

Conditions
ConditionsYield
In ethanol; water High Pressure; mixt. sodium 1-naphthalenesulfonate and AgNO3 in water was stirred for 5min and filtered, pyrazine in EtOH was added, transferred to Teflon-lin ed stainless steel autoclave and heated at 140°C for 1 day; cooling to room temp. at 10°C/h; elem. anal.;85%
130-14-3

sodium 1-naphthalenesulfonate

63536-46-9

1-ethylquinoxaline-2(1H)-one

1-ethyl-3-(2-(naphthalene-1-sulfonyl)-1-phenylethyl)quinoxaline-2(1H)-one

Conditions
ConditionsYield
With dipotassium peroxodisulfate In water at 70℃; for 24h; Green chemistry;85%
130-14-3

sodium 1-naphthalenesulfonate

13139-86-1

4-methoxyphenyl magnesium bromide

27331-33-5

1-(4-methoxyphenyl)naphthalene

Conditions
ConditionsYield
With bis(tricyclohexylphosphine)nickel(II) dichloride In tetrahydrofuran at 20℃; for 20h; Sealed tube; Inert atmosphere;83%
130-14-3

sodium 1-naphthalenesulfonate

529-36-2

1-Naphthalenethiol

Conditions
ConditionsYield
With triphenylphosphine; 18-crown-6 ether; iodine In benzene for 35h; Heating;70%
With 18-crown-6 ether; iodine; triphenylphosphine In benzene for 35h; Heating;70 % Chromat.
Multi-step reaction with 2 steps
1: PCl5 / 125 °C / aus bei 180grad getrocknetem Edukt1 und Behandeln nach dem Abkuehlen mit Eis und mit Wasser
2: zinc dust; water / 60 °C / dann bei 70grad, anschliessend Behandeln mit verd. Salzsaeure und Zinkstaub
View Scheme
108-99-6

3-Methylpyridine

130-14-3

sodium 1-naphthalenesulfonate

silver nitrate

[Ag(1-naphthalenesulfonate)(β-picoline)2]

Conditions
ConditionsYield
In water High Pressure; mixt. sodium 1-naphthalenesulfonate and AgNO3 in water was stirred for 5min and filtered, picoline was added, react. mixt. was transferred to T eflon-lined stainless steel autoclave and heated at 140°C for 1 day; cooling to room temp. at 10°C/h; elem. anal.;70%
100-97-0

hexamethylenetetramine

130-14-3

sodium 1-naphthalenesulfonate

silver nitrate

[Ag(1-naphthalenesulfonate)(hexamethylenetetramine)]*H2O

Conditions
ConditionsYield
With NH4OH In water; acetonitrile aq. soln. hexamethylenetetramine was added dropwise to soln. AgNO3 and sodium 1-naphthalenesulfonate in aq. MeCN (1:1) for 10 min; aq. soln. NH3 was added and kept in the dark for several days; elem. anal.;70%
130-14-3

sodium 1-naphthalenesulfonate

silver nitrate

603-35-0

triphenylphosphine

895139-18-1

tris(triphenylphosphine)(1-naphthalenesulfonato)silver(I)

Conditions
ConditionsYield
In methanol; water mixt. of Na salt of ligand and AgNO3 in H2O stirred for 5 min; filtered;PPh3 in MeOH added to filtrate; ppt. dissolved in min. MeCN; crystd. by slow evapn. in the dark for several d; elem. anal.;67%

Sodium 1-naphthalenesulfonate Specification

The Sodium 1-naphthalenesulfonate, with the CAS registry number 130-14-3 and EINECS registry number 204-976-0, has the systematic name of sodium naphthalene-1-sulfonate. It belongs to the product category of Intermediates of Dyes and Pigments. And the molecular formula of the chemical is C10H7NaO3S.

The characteristics of this chemical are as followings: (1)H-Bond Donor 0; (2)H-Bond Acceptor 3; (3)Rotatable Bond Count 1; (4)Exact Mass 230.001359; (5)MonoIsotopic Mass 230.001359; (6)Topological Polar Surface Area 65.6; (7)Heavy Atom Count 15; (8)Formal Charge 0; (9)Complexity 296; (10)Isotope Atom Count 0; (11)Defined Atom StereoCenter Count 0; (12)Undefined Atom StereoCenter Count 0; (13)Defined Bond StereoCenter Count 0; (14)Undefined Bond StereoCenter Count 0; (15)Covalently-Bonded Unit Count 2.

Uses of Sodium 1-naphthalenesulfonate: It can be used to produce naphthalene-1-sulfonyl chloride. This reaction will need reagent POCl3, menstruum acetonitrile and tetrahydrothiophene 1,1-dioxide. The reaction time is 40 minutes with temperature of 68-72°C, and the yield is about 94%.   

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: [Na+].[O-]S(=O)(=O)c2cccc1ccccc12
(2)InChI: InChI=1/C10H8O3S.Na/c11-14(12,13)10-7-3-5-8-4-1-2-6-9(8)10;/h1-7H,(H,11,12,13);/q;+1/p-1
(3)InChIKey: HIEHAIZHJZLEPQ-REWHXWOFAJ

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